Exhaust gas treatment system and method for treating an exhaust gas stream

专利摘要:
An exhaust gas treatment system arranged for the treatment of single exhaust gas is presented. According to the present invention, the exhaust gas treatment system comprises: - a first reduction catalyst device arranged pre-reducing nitrogen oxides NOX in said exhaust gas stream utilizing compounds comprising one or more carbon dioxide CO and the hydrocarbons HC which are included in said exhaust gas stream when said exhaust gas reducing catalyst; a particulate filter, which is arranged downstream of said first reduction catalyst device for capturing and oxidizing soot particles in said exhaust stream; a second dosing device arranged downstream of the name particle filter and arranged to supply an additive which comprises ammonia or a substance from which the ammonia is extracted and / or released in said exhaust gas stream; and - a second reduction catalyst device arranged downstream of said second dosing device and arranged for reducing nitrogen oxides NOX in said exhaust gas stream by using said additive. Fig. 3a
公开号:SE1551109A1
申请号:SE1551109
申请日:2015-08-27
公开日:2017-02-28
发明作者:Nilsson Magnus；Birgersson Henrik
申请人:Scania Cv Ab；
IPC主号:

专利说明:

TECHNICAL FIELD The present invention relates to an exhaust gas treatment system according to the preamble of claim 1 and to a method of pre-treating an exhaust stream according to the preamble of claim 17.
The present invention also relates to a computer program and end computer program product which implement the method according to the invention.
Background The following background description is a description of the background of the present invention, and thus does not necessarily constitute prior art.
Due to increased government interests regarding pollution and air quality, especially in urban areas, emission standards and emission rules for internal combustion engines have been developed in many jurisdictions.
Such emission or emission standards often constitute requirement sets which define acceptable limits on exhaust emissions from internal combustion engines in, for example, vehicles. For example, nitrogen emission levels are often regulated NOW hydrocarbons Cgg, carbon monoxide CO and particulate matter PM for most types of vehicles in these standards. Vehicles equipped with internal combustion engines typically give rise to these emissions to varying degrees. This document describes the invention mainly for its application in vehicles. However, the invention can be used in essentially all applications where internal combustion engines are used, for example in vehicles, such as in ships or aircraft / helicopters, whereby rules and / or 10 standards for these applications limit the emissions from the internal combustion engines.
In a penalty to meet such emission standards, the exhaust gases caused by the combustion engine's combustion are treated (purified).
A common method of treating exhaust gases from a single-combustion engine consists of a so-called catalytic purification process, which is why vehicles equipped with a single-combustion engine usually comprise at least one catalyst. There are different types of catalysts, where the different types can be suitable depending on, for example, which combustion concepts, combustion strategies and / or industry types are used in the vehicles and / or which types of compounds in the exhaust stream are to be purified. At least nitrous gases (nitrogen monoxide, nitrogen dioxide), in this document called nitrogen oxides NOX, vehicles often comprise a catalyst where an additive is added to the combustion engine combustion exhaust gas stream to bring about a reduction of nitrogen oxides NOX mainly to nitrogen gas and water vapor. This is described in more detail below.
A common type of catalyst in this type of reduction, especially for heavy vehicles, is SCR (SelectiveCatalytic Reduction) catalysts. SCR catalysts usually use ammonia NH3, or a compound from which ammonia can be generated / formed, as an additive which is used for the reduction of the nitrogen oxides NOX in the exhaust gases. The additive is injected into the exhaust gas stream from the internal combustion engine upstream of the catalyst. The additive fed to the catalyst is adsorbed (stored) in the catalyst, in the form of ammonia NH3, whereby a redox reaction 10 can take place between nitrogen oxides NOX in the exhaust gases and ammonia NH3 available through the additive.
A modern internal combustion engine is a system where there is solitude and mutual influence between engine and exhaust gas treatment. In particular, there is a link between the ability to reduce nitrogen oxides NOX in the exhaust gas treatment system and the fuel efficiency of the internal combustion engine. The pre-combustion engine has a connection between engine fuel efficiency / efficiency and its produced nitrogen oxides NOX. This connection indicates that for a given system there is a positive connection between produced nitrogen oxides NOX and industry efficiency, ie that an engine that is allowed to emit more nitrogen oxides NOX can be made to consume less fuel by, for example, the injection time can be chosen more optimally, which can no higher combustion efficiency. Correspondingly, finnsofta put a negative connection between a produced particulate mass PM and the industry efficiency, that is to say that an increased emitted particulate mass PM from the engine connects to an increase in fuel consumption. These relationships form the background for the widespread use of exhaust gas treatment systems including a SCR catalyst, where it is intended to optimize the industry and particulate matter against a relatively larger mass-produced nitrogen oxides NOX. A reduction of these nitrogen oxides NOX is then carried out in the exhaust gas treatment system, which thus may include an SCR catalyst. Through an integrated visual wide-engine and exhaust gas treatment system design, where engine and exhaust gas treatment complement each other, hog industry efficiency can therefore be achieved together with low emissions of both PM particles and NOX nitrogen oxides. Brief Description of the Invention To some extent, the performance of exhaust gas treatment systems can be increased by increasing the substrate volumes contained in the exhaust gas treatment systems, which in particular reduces the losses due to uneven distribution of exhaust gas flow through the substrates. At the same time a larger substrate volume gains in fuel efficiency from the higher conversion rate. Larger substrate volumes also meant an increased cost. It is thus important to be able to make optimal use of the exhaust gas treatment systems, for example by avoiding oversizing and / or by limiting the distribution of the exhaust gas treatment systems in size and / or its manufacturing cost.
The function and efficiency of catalysts in general, and of reduction catalysts in particular, are strongly dependent on the temperature above the reduction catalyst. In this document, a temperature above the reduction catalyst meant a temperature in / at / for the exhaust gas flow through the reduction catalyst. The substrate will assume this temperature due to its ability to heat exchange. At a low temperature above the reduction catalyst, the reduction of nitrogen oxides NOX is typically ineffective. The NO2 / NOX content in the exhaust gases constitutes a certain possibility of increasing the catalytic activity, even at lower exhaust gas temperatures. However, the temperature and the NO2 / NOX content of the reduction catalyst are generally difficult to control, as it largely depends on a number of factors, for example on how the driver drives the vehicle. For example, the temperature over the reduction catalyst depends on the torque required by a driver and / or cruise control , of the appearance of the road section on which the vehicle is located and / or of the driver's driving style. Previously known exhaust gas treatment systems, such as the system described below in detail which many manufacturers have used to meet the Euro VI emission standard (hereinafter referred to as the "EuroVI system"), include an oxidation catalyst, a diesel particulate filter and a reduction catalyst, exhibiting problems related to large thermal masses. / filters as well as the large thermal mass / inertia of the rest of the exhaust gas treatment system, including for example exhaust pipes, silencers and various connections. In cold starts, for example, when both the engine and exhaust gas treatment system are cold, and in the case of load application from low exhaust temperatures, when more torque is previously required, for example when light city grain passes into country road grain or after idle and power take-off operation, above all the diesel particulate filter's large thermal mass such prior exhaust treatment systems. As a result, for example cold starts and in vehicle operation with temperature and / or river transient elements, the function of the pre-reduction catalyst, and thereby the reduction of nitrogen oxides NOX, is assembled. This pre-accumulation can result in substandard exhaust gas purification, which risks polluting millions without further ado. In addition, the pre-assembly of the reduction catalyst function increases the risk of not being required by the authorities to meet the exhaust gas purification requirements. Industry consumption can also be negatively affected by the assembled function, since industry energy ideas may need to be used to, via various temperature-raising measures, increase the temperature and efficiency of the reduction catalyst.
It is an object of the present invention to improve the purification of the exhaust gases in an exhaust gas treatment system, at the same time as the conditions for achieving a higher industry efficiency are improved.
These objects are achieved by the above-mentioned exhaust gas treatment system according to the cited part of claim 1. The object is also achieved by the above-mentioned method according to the cited part of claim 17. The object is also achieved by the above-mentioned computer program and the computer program product.
According to the present invention, there is provided an exhaust gas treatment system which is arranged for treating single exhaust gas stream from an internal combustion engine. The exhaust gas treatment system comprises a first reduction catalyst device arranged to reduce nitrogen oxides NOX in the exhaust stream by utilizing compounds comprising one or more carbon dioxide CO and the hydrocarbons HC which are included in exhaust gas streams the exhaust stream reaches the first reduction catalyst device. In this document, the term hydrocarbon HC is generally used for hydrocarbon compounds CaH® which include compounds comprising carbon C and hydrogen H in different proportions. Thus, the first reduction of nitrogen oxides NOX according to the present invention is performed based on compounds that are naturally present or created / introduced into the exhaust gas stream from the engine. Thereby, the need for the supply of additives comprising ammonia upstream of the first reduction catalyst device can be eliminated according to certain embodiments of the present invention. This can also be described as the first reduction of nitrogen oxides NOX in the first reduction catalyst device is only exhaust gas based, whereby nitrogen oxides NOX in the exhaust gases are reduced by utilizing compounds which occur naturally or are created in the exhaust gases already at the internal combustion engine. The exhaust gas treatment system further comprises a particulate filter, which is arranged downstream of the first reduction catalyst device for capturing and oxidizing soot particles in the exhaust stream.
The exhaust gas treatment system comprises a second dosing device arranged downstream of the particulate filter to supply an additive which comprises ammonia or a substance from which ammonia can be recovered and / or released in the exhaust gas stream.
The exhaust gas treatment system also includes a second reduction catalyst device disposed downstream of the second dosing device for reducing nitrogen oxides NOX in the exhaust gas stream by utilizing the additive supplied by the second dosing device.
Thus, by utilizing the present invention, compounds that are naturally present or created / introduced into the exhaust gas stream can be utilized in the reduction of nitrogen oxides NOX by means of the first reduction catalyst device. According to several embodiments, the requirement that a first dosing device for dosing additives, such as ammonia or AdBlue, be mounted upstream of the first reduction catalyst device is eliminated, which reduces the manufacturing costs and service costs of the vehicle. In addition, it reduces the technical complexity . In other words, then, several embodiments of the present invention require the use of a first dosing device, nor any devices for supplying additives to a first dosing device. The exhaust gas treatment system also need not include any first evaporator unit or any 10 first mixer upstream of the first reduction catalyst device. In addition, the vehicle operating costs of the vehicle are reduced because the consumption of additives, such as for example AdBlue or the like, is reduced when the first reduction with the first reduction catalyst is carried out by means of compounds present in the exhaust stream instead of by means of additives.
In addition, the reduction of nitrogen oxides NOX according to the present invention can continue even if the additive runs out, since the reduction can be performed based on compounds present in the exhaust stream from the engine.
By utilizing the present invention, a more temperature-efficient treatment of the exhaust gases is obtained by the upstream mounted first reduction catalyst device in the exhaust gas treatment system according to the invention at certain operating types can operate at more favorable temperatures the temperatures of the downstream mounted second reduction catalyst device. For example, it reaches the first reduction catalyst device at cold starts and application from low temperatures has previous operating temperatures at which an effective reduction of nitrogen oxides NOX is obtained. Thus, according to the invention, the available heat is utilized in a more energy-efficient manner, which results in an earlier and / or more efficient reduction of nitrogen oxides NOX, for example in cold starts and in applications from low exhaust temperatures, used as has been possible with the previously known exhaust gas treatment systems.
In certain other operating types, the second downstream-mounted reduction catalyst device can correspondingly operate at more favorable temperatures than the temperatures of the first upstream-mounted reduction catalyst device. By utilizing the invention, different thermal inertia is obtained for the first and for the second reduction catalyst device, which means that these first and second reduction catalyst devices can be optimized differently with respect to activity and selectivity. In this way, the first and second reduction catalyst devices can be optimized from a system perspective, that is to say from a perspective that looks at the entire exhaust gas treatment system function, and can therefore be used together to provide totally more efficient purification of the exhaust gases than the separately optimized catalysts could provide. These optimizations of the first and second reduction catalyst devices according to the invention can be used to give this overall more efficient cleaning in, for example, cold start, but also substantially all vehicle operation, since temperature and / or flow transient elements often occur even in normal vehicle operation. As mentioned above, the invention can also be used for exhaust gas purification in other units of vehicles, such as in different types of vehicles, whereby an overall more efficient purification of the exhaust gases from the unit is obtained.
The present invention takes advantage of the thermal inertia / mass of the particle filter to the advantage of the pre-function by, based on this inertia, optimizing the function of both the first and the second reduction catalyst device. Thereby the present invention is obtained an interaction / symbiosis between the first reduction catalyst device, which is optimized for the first thermal mass and the first temperature function / temperature course to which it is exposed, and the second reduction catalyst device, which is optimized for the second thermal mass and the second temperature course to which it is exposed.
The first reduction catalyst device and / or the second reduction catalyst device can thus be optimized based on properties, for example catalytic properties, before the second reduction catalyst device and / or for the first reduction catalyst device. For example, the hard second reduction catalyst device can be designed / selected so that its catalytic properties at low temperatures become less efficient, which enables its catalytic properties at high temperatures to be optimized. If he considers these catalytic properties of the second reduction catalyst device, then the catalytic properties of the first reduction catalyst device can then be optimized in such a way that it need not be as efficient at high temperatures.
These possibilities for optimizing the first reduction catalyst device and / or the second reduction catalyst device mean that the present invention provides an exhaust gas purification which is lamped pre-emissions which occur in essentially all types of exit falls, especially for strongly transient operation which gives a varying temperature and / or flow profile. Transient operation can, for example, include a relatively large number of starts and decelerations for the vehicle or a relatively large number of ups and downs. Since relatively many vehicles, such as buses which often stop at stops and / or vehicles which are driven in city traffic or hilly topography, experience such transient operation, the present invention provides an important and very useful exhaust gas purification, which overall reduces the emissions from the vehicles in which it is implemented.
The present invention thus uses the previously problematic thermal mass and heat exchange of primarily the particulate filter in the EuroVI system as a positive property. The exhaust gas treatment system according to the present invention can, in the same way as the EuroVI system, contribute heat to the exhaust stream and the downstream mounted reduction catalyst device for shorter periods of relaxation or other low temperature operation if this low temperature operation has been carried out by operation with higher working temperatures. The particulate filter is then, due to destermic inertia, hotter than the exhaust stream, so the exhaust stream can be heated by the particulate filter.
In addition, this good property is thus supplemented by the fact that the first reduction catalyst device placed upstream, especially in transient operation, can utilize the hog temperature which arises during start-up. Thus, the first reduction catalyst device experiences a higher temperature after application than the second reduction catalyst device experiences. This higher temperature of the pre-reduction catalyst device is utilized by the present invention to improve the NOX reduction of the pre-reduction catalyst device. The present invention, which utilizes two reduction catalyst devices, can utilize both of these positive properties by enabling NOX reduction with a small thermal inertia, i.e. the exhaust gas treatment system according to the invention comprises both a NOX conversion upstream of a large thermal inertia and a NOX conversion. downstream a large thermal inertia. The exhaust gas treatment system according to the present invention can then utilize available heat in a maximum energy efficient manner, which means that even the fast and "unfiltered" heat experienced by the first upstream reduction catalyst device can be used to make the exhaust gas treatment system according to the invention efficient.
The exhaust gas treatment system of the present invention has the potential to meet the emission / emission requirements of the Euro VI emission standard. In addition, the exhaust gas treatment system of the present invention has the potential to meet the emission / emission requirements of several other existing and / or future emission standards.
The exhaust gas treatment system of the present invention is compactly arranged, since in relation to the degree of performance / purification it can deliver, it comprises few units in the exhaust gas treatment system. These relatively few units, for a selectively awaited exhaust gas purification system according to the present invention, also do not have to be large in volume. When number units, and the size of these units, are kept down by the present invention, the exhaust back pressure can also be limited, which gives lower fuel consumption for the vehicle. Catalytic performance per unit volume of substrate can be exchanged for a smaller substrate volume to obtain some catalytic purification. Combined exhaust gas purifier with a predetermined size and / or a predetermined external geometry, which is often the case in vehicles with limited space for the exhaust gas treatment system, a smaller volume of substrate means that a larger volume within the predetermined purge device can be used for distribution, mixing and irrigation of exhaust gas. This means that the exhaust back pressure can be reduced for an exhaust gas cleaning device with a predetermined size and / or a predetermined external geometry if the performance per substrate volume unit is increased. Thus, the total volume of the pre-exhaust gas treatment system of the invention can be reduced as compared with at least some prior art systems. Alternatively, the 10 13 exhaust back pressure can be reduced by utilizing the present invention.
By utilizing the present invention, the need for an exhaust gas recirculation system (EGR) can also be reduced or completely eliminated. Reducing the need for utilization of exhaust gas recirculation systems has, among other things, advantages related to robustness, gas exchange complexity and power output.
In the new manufacture of vehicles, the system of the present invention can be easily assembled at a limited cost, since the separate oxidation catalyst DOC, i.e. the separate substrate for the oxidation catalyst DOC and the incorporation of this substrate, which existed in previous kanda systems during manufacture, are then replaced with the forester reduction catalyst device. Even retrofitting of an exhaust gas treatment system according to the present invention can be easily carried out, since the oxidation catalyst DOC present in the prior art system can be replaced by the first reduction catalyst device according to the present invention also in already manufactured vehicles. When compounds comprising carbon monoxide CO and / or the hydrocarbons HC and which occur naturally or are introduced / introduced into the exhaust stream are used in the reduction of nitrogen oxides NOX according to the present invention, no further dosing device will be required either. In order to achieve sufficient nitrogen dioxide-based (NO 2 -based) sotoxidation, the engine ratio of nitrogen oxides to soot (NOX / soot ratio) according to certain embodiments of the present invention may need to meet certain criteria. According to one embodiment of the present invention, the particulate filter is a conventional uncoated particulate filter.
According to another embodiment of the present invention arden oxidizing coating, for example comprising noble metal, which in EuroVI systems is present in the oxidation catalyst DOCistallet at least partially implemented in the particulate filter cDPF, whereby conditions for a sufficient NO 2 -based oxidation can be obtained. Thereby a compact design of the exhaust gas treatment system according to the invention is obtained. By using a diesel particulate filter cDPF co-oxidation catalyst properties an increased predictability for the formation of nitrogen dioxides NO2 can also be obtained. This is due to deactivation of the catalytic deactivation agents, e.g. This makes catalysts of relatively short physical length more susceptible to these poisonings than catalysts of larger physical length. For example, when noble metal, such as Platinum, is applied to the physically long diesel particulate filter cDPF, instead of to the physically shorter oxidation catalyst DOC, more stable levels of nitrogen dioxide NO2 can potentially be obtained over time.
According to an embodiment of the present invention, the particle filter comprises at least in part a catalytically reducing coating arranged for the reduction of nitrogen oxides NOX.
According to an embodiment of the present invention, the first reduction catalyst device constitutes an at least partially protective substrate upstream of an oxidizing coating, where the deoxidizing coating may be included in an oxidation catalyst or in a particle filter coated with, for example, noble metal. The catalytic coating for the first reduction catalyst device can, according to one embodiment, be chosen robust against chemical poisoning, which over time can give a more stable level for the ratio of intermediate nitrogen dioxide and nitrogen oxides NO2 / NOX which reach the second reduction catalyst device.
In addition, an adaptation / calibration of several NOX sensors in the exhaust gas treatment system can be easily performed in the system according to the present invention, since the sensors can be exposed to the same NOX level while the emission levels can be kept at reasonable levels during the adaptation / calibration. For the EuroVI system, for example, the adaptation / calibration has often resulted in the emissions becoming too high during, and even partly after, the actual adaptation / calibration.
As mentioned above, the first and second reduction catalyst devices can be optimized individually, and taking into account the operation of the entire exhaust gas treatment system, which can provide an overall very efficient purification of the exhaust gases. This individual optimization can also be used to reduce one or more of the volumes occupied by the first and second reduction catalyst devices, whereby a compact exhaust gas purification system is obtained.
According to one embodiment, the present invention also enables control of a ratio NO¿¿ / NO & ¿between the amount of nitrogen dioxide NOÃQ and the amount of nitrogen oxides NO & ¿for the second reduction step, which means that the system can avoid the high values of this ratio, for example avoid NO¿¿ / NO & ¿> 50%, and that the system, by increasing the dosage, can increase the value for the ratio NO¿¿ / NO & ¿when the value is too low, for example if NO¿¿ / NO & ¿<50%. The value of the NO2 / NO2 ratio may, for example, by utilizing an embodiment of the present invention, be increased by decreasing the level of nitrogen oxides NO2. The ratio N022 / NOÄ2 edge stores the value, for example, after the system has aged for a period of time. The present invention thus provides an opportunity to counteract the time accumulated, and for the system the negative property, which gives too low values for the ratio NO22 / NO22. Thus, by utilizing the present invention, the content of nitrogen dioxide NO22 can be actively controlled, which is made possible by the NO22 level being adjusted upstream of the catalytically oxidizing coating, for example including noble metal, in the oxidation catalyst or in the particulate filter. This control of the NO22 / N / A22 ratio such as higher conversion of NOx, also the possibility to reduce the emissions specifically of nitrogen dioxide NO2, which gives a very toxic and strong foul-smelling emission. This can provide benefits in the event of the future introduction of a separate legal requirement for nitrogen dioxide N02, as well as the opportunity to reduce harmful emissions of nitrogen dioxide N02.
This can be compared with, for example, the EuroVI system, in which the proportion of nitrogen dioxide NO2 provided during exhaust gas purification is not controllable in the exhaust gas treatment system itself.
In other words, the active control of nitrous oxide NO22 is enabled in the practice of the present invention, where the active control can be utilized to increase nitrate dioxide NO22 in the driving cases for which it is necessary. Hereby an exhaust gas treatment system can be selected / specified which requires less noble metal and thus also cheaper to manufacture. If the proportion of the total conversion of nitrogen oxides N0X occurs via a fast reaction wave, ie via fast SCR ("solid SCR") where the reduction takes place via reaction waves over both nitrogen oxide N0 and nitrogen dioxide N02, can be increased by the active control of the content nitrogen dioxide NO¿¿ so the requirements for the catalyst volume can also be reduced.
According to an embodiment of the present invention, the first reduction catalyst device in the exhaust gas treatment system is active at a storage reduction temperature range Tæd an detoxification temperature range TM, as required for the nitrogen dioxide-based sotoxidation in the particulate filter DPF. As an example, it can be mentioned that the nitrogen dioxide-based deoxidation in the particle filter DPF can take place at temperatures exceeding 275 ° C. As a result, the reduction of nitrogen oxides NOX in the first reduction catalyst device does not compete significantly with the sotoxidation in the particle filter DPF as they are active within at least partially different temperature range Tæd # TM. For example, a selected and optimized first reduction catalyst device can achieve a significant conversion of nitrogen oxides NOX even at about 200 ° C, which means that this first reduction catalyst device does not have to compete with the sotoxidation performance of the co-particle filter, whereby an effective sotoxidation is obtained.
By utilizing the present invention, secondary emissions, such as emissions of ammonia NH3 and / or nitrous oxide (nitrous oxide) NO2, can be reduced in relation to a given degree of conversion and / or a given NOX level. A catalyst, for example an SC (Slip Catalyst), which may be included in the second reduction step if the emissions for certain jurisdictions are to be reduced to very low levels, may have some selectivity towards, for example, nitrous oxide N2O, which has made the NOX level lower by using the additional reduction step of the present invention also switches down the resulting levels of nitrous oxide N 2 O. The resulting levels of ammonia NH 3 can be degraded accordingly as the present invention is utilized.
By utilizing the present invention, a better fuel optimization can be obtained for the vehicle, since it thereby has the potential to control the engine more fuel efficiently, whereby a higher efficiency of engine is maintained. Thus, a performance gain and / or a reduced emission of carbon dioxide CO 2 can be obtained when the present invention is utilized.
BRIEF DESCRIPTION OF THE DRAWINGS The invention will be further elucidated below with reference to the accompanying drawings, in which like reference numerals are used for like parts, and in which: Figure 1 shows an exemplary vehicle which may include the present invention, Figure 2 shows a traditional exhaust gas treatment system. various embodiments of the present invention, Figure 4 shows a flow chart of the exhaust gas treatment process of the present invention, Figure 5 shows a control unit according to the present invention, Figure 6 schematically shows a multifunctional grinding catalyst.
Description of Preferred Embodiments Figure 1 schematically shows an exemplary vehicle 100 including an exhaust gas treatment system 150, which may be an exhaust gas treatment system 150 according to an embodiment of the present invention. The driveline comprises a single-combustion engine 101, which in a conventional manner, via a shaft 102 extending on the internal combustion engine 101, usually via a flywheel, is connected to a gearbox 103 via a clutch 106.
The internal combustion engine 101 is controlled by the vehicle control system via a single control unit 115. Likewise, the clutch 106 and the gearbox 103 can be controlled by the vehicle control system by means of one or more suitable control units (not shown). The vehicle's driveline can be of a different type, such as a type with a conventional automatic transmission, a type with a hybrid driveline, etc.
A shaft 107 emanating from the gearbox 103 drives the drive wheels 113, 114 via an end shaft 108, such as e.g. a conventional differential, and drive shafts 104, 105 connected to said end shaft 108.
The vehicle 100 further includes an exhaust gas treatment system / exhaust purification system 150 pre-treatment / purification of exhaust emissions resulting from combustion in the combustion chamber of the internal combustion engine 101, which may be cylinders.
Figure 2 shows a former edge of the exhaust gas treatment system 250, which may illustrate the above-mentioned EuroVI system, and with which an exhaust line 202 is connected to an internal combustion engine 201, where the exhaust gases generated during combustion, the stray exhaust stream 203, are indicated by arrows. The exhaust stream 203 is led to a Diesel Particulate Filter (DPF) 220 via a Diesel OxidationCatalyst (DOC) 210. During combustion in the internal combustion engine, soot particles are formed, and the DPF 220 particulate filter is used to capture these soot particles. The exhaust stream 203 is led through a filter structure where soot particles are captured from the passing exhaust stream 203 and stored in the particulate filter 220.
The oxidation catalyst DOC 210 has several functions and is normally used primarily to oxidize the remaining hydrocarbons CJ &) (also called HC) and carbon monoxide CO in the exhaust stream 203 to carbon dioxide CO2 and water H2O. The oxidation catalyst DOC 210 can also oxidize a large proportion of NOox . The oxidation of nitrogen monoxide NO to nitrogen dioxide NO2 is important for the nitrogen dioxide-based deoxidation in the filter and is furthermore advantageous in the event of a subsequent subsequent reduction of nitrogen oxides NOX. In this regard, the exhaust gas treatment system 250 further comprises SCR (SelectiveCatalytic Reduction) catalyst 230 arranged downstream of the particulate filter DPF 220. SCR catalysts use ammonia NH 3, or a composition from which ammonia can be generated / formed, such as e.g. urea, as an additive to reduce the amount of nitrogen oxides NOX in the exhaust gas stream. However, the reaction rate of this reduction is affected by the ratio of nitrogen monoxide NO to nitrogen dioxide NO2 in the exhaust stream, so that the reaction of the reduction is positively affected by the previous oxidation of NO to NO2 in the oxidation catalyst DOC. This applies up to every one equivalent to approximately 50% for the molar ratio NO2 / NOX. Increased proportions for the molar ratio NO2 / NOX, ie the value in excess of 50%, have a strongly negative effect on the reaction rate.
As mentioned above, the SCR catalyst 230 requires additives to reduce the concentration of a compound such as exemplary whey oxides NOX in the exhaust stream 203. This additive is injected into the exhaust stream upstream of the SCR catalyst 230 (not shown in Figure 2). This additive is traditionally based on ammonia and / or urea, or consists of a substance from which ammonia can be extracted or released, and may, for example, consist of AdBlue, which in principle constitutes urea mixed with water. Urea forms ammonia partly on heating (thermolysis) and partly on heterogeneous catalysis on an oxidizing surface (hydrolysis), which may for example consist of titanium dioxide TiO 2 within the SCR catalyst. The exhaust gas treatment system may also include a separate hydrolysis catalyst.
The exhaust gas treatment system 250 is also provided with Ammonia Slip Catalyst (ASC) 240 which is arranged to oxidize an excess of ammonia which may remain after the SCR catalyst 230.
The exhaust gas treatment system 250 is also provided with one or more sensors, such as one or more NOX and / or temperature sensors 261, 262, 263, 264 for detecting nitrogen oxides and / or temperatures in the exhaust gas treatment system.
The previously known exhaust gas treatment system shown in Figure 2, i.e. the EuroVI system, has a problem in catalytic converters being efficient heat exchangers, which together with the rest of the exhaust system, including for example exhaust pipe 202 and materials and space for sound evaporation and various connections, have a large thermal mass / inertia When starting when the catalyst temperature is below its optimum working temperature, which can be around 300 ° C, for example, and when starting from low exhaust temperatures, which for example occur when urban driving turns into country road driving or after idle and power take-off operation, the exhaust gas temperature is filtered by this large thermal mass. This affects the function, and thereby the efficiency of the pre-reduction of, for example, nitrogen oxides NOX of the SCR catalyst 230, which may result in a substandard exhaust purification 10 22 provided by the system shown in Figure 2. This allows a smaller amount of nitrogen oxides NOX released from the engine 10l if the exhaust gas purification had been efficient, which could lead to demands for a more complex engine and / or lower industry efficiency.
In the previously known exhaust gas treatment system, there is also a risk that the relatively cold reducing agent locally cools down the exhaust pipe parts and thus can give rise to precipitations. This risk of precipitation in the downstream injection increases if the amount of reducing agent injected must be large.
Among other things, to compensate for the limited supply of heat / temperature at, for example, cold starts and low load operation, so-called fast SCR ("fixed SCR") can be used, the reduction being controlled to as far as possible via reaction waves over both nitrogen oxide NO and nitrogen dioxide NO2. In the case of fast SCR, the reaction uses equal parts of nitrous oxide NO and nitrogen dioxide NO2, which means that an optimal value of the molar ratio NO2 / NOX is close to 50%.
For certain catalyst temperature and flow conditions, ie for a certain residence time in the catalyst ("SpaceVelocity"), there is a risk that a non-advantageous proportion of nitrogen dioxide NO2 is obtained. In particular, there is a risk that the NO2 / NOX ratio exceeds 50%, which can be a real problem for exhaust gas purification. An optimization of the NO2 / NOX ratio for the above-mentioned critical low-temperature operating cases thus risks giving an excessively high proportion of nitrogen dioxide NO2 in other operating cases at, for example, higher temperatures. This higher proportion of nitrogen dioxides NO2 results in larger volume requirements for the SCR catalyst and / or in a limitation of the amount of nitrogen oxides emitted from the engine and thus in a lower fuel efficiency for the vehicle. In addition, there is a risk that the higher proportion of nitrogen dioxides N02 also results in emissions of nitrous oxide N20. These risks of a non-beneficial proportion of nitrogen dioxide N02 also exist due to aging of the system. For example, the ratio N02 / N0 , which is known as a surveyor's specification which in the state of the elderly gives an even higher end, even N02 / N0X must be used to cover the height, and be able to compensate for, the old age. Also a lack of control robustness against dosing errors for quantity reducing agents and / or a lack of control robustness against single sensor error detection felt at high NOX conversion rates constitute a problem for the goose treatment system.
Figure 3a schematically shows a goose treatment system 350 according to an embodiment of the present invention, which while goose line 302 is connected to an internal combustion engine 301. Exhaust gases generated during combustion in the engine 301 are led in a single gas stream 303. Reducing nitrogen oxides NOx in the exhaust gas stream 303 by utilized compounds included one or more of the carbon monoxide C0 and hydrocarbons HC, these compounds being entrapped in the exhaust gas stream 303 when it reaches the reduction reduction gas reactor device 311. More specifically, the pre-reduction boiler assembly device 331 uses one or more compounds which naturally contain or dispense in the exhaust gases from an internal combustion engine 301 in the reduction of the nitrogen oxides NOx in the exhaust gas drum 303. 24 According to an embodiment of the present invention, the present invention may be illustrated by the present invention. NOX -) N2 + co2 + Hgo; (Eq. 1) ochco + Nox -) Ng + co2. (Eq. 2) In these simplified reaction formulas, HC corresponds to one or more hydrocarbon compounds CJH. Both Equation 1 and Equation 2 give a reduction of nitrogen oxides NOX, whereby HC and CO, respectively, are used in the reduction.
According to one embodiment of the present invention, the internal combustion engine 301 may be controlled to burn within one or more selected operating ranges the fuel injected into the engine in such a manner that elevated levels of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC are present in the exhaust stream 303. used in the first reduction.
The exhaust gas treatment system 350 of the present invention includes downstream of the first reduction catalyst device 331 a particulate filter 320, which is arranged to capture and oxidize soot particles. The exhaust stream 303 is passed through the particulate filter structure, soot particles being trapped in the filter structure and the passing gas.
According to an embodiment of the present invention, the exhaust gas treatment system 350 comprises a first oxidation catalyst 311 arranged upstream of the first reduction catalyst 331.
The first oxidation catalyst 311 is then arranged to perform a first oxidation and / or decomposition of compounds comprising one or more of nitrogen, carbon and hydrogen in the exhaust stream 303 and / or to create an exotherm.
According to one embodiment of the invention, the particulate filter 320 is arranged so that the particulate filter 320 is the first exhaust treatment system component as the exhaust stream 303 after passing the first reduction catalyst device 331. In other words, the particulate filter 320 according to the embodiment is connected to
According to another embodiment of the present invention, the exhaust gas treatment system 350 includes a second oxidation catalyst 312 disposed downstream of the first reduction catalyst device 331 and the upstream particle filter 320 to perform a second oxidation and / or decomposition of compounds comprising one or more of nitrogen, carbon and hydrogen and liquefied gas. create an exotherm.
According to an embodiment of the present invention, the exhaust gas treatment system 350 comprises a third oxidation catalyst 313 disposed downstream of the particulate filter 320 and upstream of the second reduction catalyst device 332 for performing third oxidation and / or decomposition of compounds comprising one or more of nitrogen, carbon and hydrogen in said create an exotherm.
As described in more detail below, according to one embodiment, the first reduction catalyst device 331 may comprise a first catalytic reduction catalyst CR1, a first 1026 catalytic reduction catalyst CR1 downstream followed by a first slip catalyst SC1, a first slip catalyst SC1 downstream sequence of a first catalyst , or only a first slip catalyst SC1.
According to an embodiment of the present invention, the particle filter DPF 320 is a traditional non-coated particle filter, i.e. a particle filter DPF without any catalytic oxidizing coating.
According to another embodiment of the present invention, the particle filter 320 is at least partially coated with a catalytic oxidizing coating, wherein this oxidizing coating may comprise at least one noble metal. That is, the particulate filter 320 may be at least partially coated with one or more noble metals, such as platinum. According to one embodiment of the present invention, the coating of the filter is arranged in the front part of the filter, i.e. connected to the inlet of the filter. This can also be expressed as the coating, for example comprising one or more noble metals, being located at the spirit of the filter where the exhaust gas stream flows into the filter. The cDPF 320 particulate filter comprising the oxidizing coating has several advantages compared to a classic DPF particulate filter without oxidizing coating. The particle filter cDPF 320 comprising the deoxidizing coating gives an improved NO2-based regeneration of the filter, i.e. an improved NO2-based sotoxidation, which can also be called passive regeneration of the filter. The particle filter cDPF 320, which includes the oxidizing coating, also provides more stable conditions for the nitrogen dioxide level N02 at the second reduction catalyst device 332. In addition, the use of the particle filter cDPF 320 comprising the 10 27 oxidizing coating allows the value of the NO2 / NOX ratio to be controlled.
The particulate filter 320, which at least partially comprises encatalytically oxidizing coating, can also more efficiently oxidize soot particles and one or more incompletely oxidized nitrogen and / or carbon compounds due to the oxidizing coating.
According to one embodiment of the present invention, the particle filter 320 is at least partially coated with encatalytically reducing coating arranged to reduce nitrogen oxides NOX.
The system according to the embodiment of the present invention intends to purify the filter from soot by a NO 2 -based passive regeneration. However, the present invention can also be advantageously utilized in active regeneration of the filter, i.e. the regeneration is initiated by an injection, for example through utilization of an injector, by industry upstream of the filter. In the case of active regeneration, the exhaust gas treatment system according to the invention has the advantage that the further reduction catalyst device itself can handle a certain NOX conversion during the time when the downstream filter arranged by the other reduction catalyst device, due to the degeneration, experiences such a high temperature that it is difficult to reach a high degree of conversion.
When utilizing the engine injection system in a single regeneration of the DPF / cDPF particulate filter, the amplifier reduction catalyst device will at least partially assist the DPF / cDPF particulate filter by partially oxidizing the fuel primarily carbon monoxide CO. This simplifies the regeneration of the particle filter DPF / cDPF compared to exhaust gas treatment systems 28 which lack a first reduction catalyst device according to the present invention.
Downstream of the particulate filter 320, the exhaust gas treatment system 350 is provided with a second metering device 372, which is arranged to supply an additive in the exhaust stream 303, this additive comprising ammonia NH 3, or a substance, for example AdBlue, from which ammonia is congenerated / formed / released, as described above. According to one embodiment of the invention, a hydrolysis catalyst and / or a mixer can be arranged in connection with the second dosing device 372. The hydrolysis catalyst can be constituted by essentially any suitable hydrolysis coating. The mixer may be arranged in connection with the second dosing device 372. The hydrolysis catalyst and / or mixer is then used to increase the rate of decomposition of urea to ammonia and / or to mix the additive with the emissions and / or to evaporate the additive.
The exhaust gas treatment system 350 also includes a second reduction catalyst device 332, which is arranged downstream of the second metering device 372. The second reduction catalyst device 332 is arranged to reduce nitrogen oxides NOX in the exhaust stream 303 by utilizing the additive.
The exhaust gas treatment system 350 may also be provided with one or more sensors, such as one or more NOX sensors 361,363, 364 and / or one or more temperature sensors 362, 363, which are arranged for determining NOX concentrations or temperatures of the exhaust gas treatment system 350. The NOX sensor 363 between the two dosing devices 371, 372, and preferably between the particle filter DPF / CDPF 320 and the second 29 dosing device 372, also makes it possible to correct the amount of additives dosed by the second dosing device 372 for nitrogen oxides NOX which can be created over the particle filter DPF / DPF 320.
The NOX sensor 364 downstream of the second reduction catalyst device 332 can be used in feedback of dosing of the additive.
The one or more sensors 361, 362, 363, 364 may be coupled to a control unit 360, which is arranged to provide one or more control signals which may be used in controlling the internal combustion engine 301 so that a desired set of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC is present in the exhaust stream 303 discharged from the internal combustion engine 301. This desired amount of compounds including one or more of carbon monoxide CO and the hydrocarbons HC is thus controlled so that the compounds can be utilized by the first reduction catalyst device 331 in the first reduction of nitrogen oxides NOX.
According to a couple of embodiments of the present invention, the active control of the internal combustion engine 301 comprises a choice of at least one injection strategy for the internal combustion engine.
According to an embodiment of the present invention, the edge times for injecting fuel into the respective cylinder of the internal combustion engine are controlled so that a desired amount of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC are present in the exhaust stream 303 released from the internal combustion engine 301.
According to an embodiment of the present invention, the injection pressure for the injections of fuel into the respective cylinder of the internal combustion engine can be controlled so that an desired amount of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC is present in the exhaust stream 303 released from the internal combustion engine 301.
According to an embodiment of the present invention, a single injection phase for an injection of fuel in the respective cylinder can be controlled so that a desired amount of compounds including one or more of carbon monoxide CO and the hydrocarbons HC are present in the exhaust stream 303 discharged from the internal combustion engine 301. Co-injection phase is referred to in this document. , for example how the pressure of the injection changes over time. A representation of (a measured for) the injection phase can for example be a time derivative of the cylinder pressure.
According to one embodiment of the present invention, the active control of the internal combustion engine 301 includes control of an ExchangeGas Recirculation (EGR) device. Internal combustion engines are provided at one inlet with air to provide a combustion lamp gas mixture for combustion together with fuel which is also the feed engine. The combustion takes place in the engine cylinders, whereby the gas mixture is burned. The combustion creates exhaust gases which leave the engine at an outlet. The exhaust return is arranged from the engine's outlet to its inlet and returns some of the exhaust gases from the outlet to the inlet. As a result, the rabbit suction losses during the air suction are reduced and the amount of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC out of the engine is adjusted.
According to an embodiment of the present invention, the exhaust gas treatment system 350 comprises a system 370 for supplying additives, which comprises at least one pump 373 10 3l arranged to supply the other 372 dosing device with additives, i.e. with for example ammonia or UIGÖ.
The system 370, according to one embodiment, provides the second 372 dosing device with liquid additives. Liquid additives can be refueled at many filling stations / gas stations where fuel is provided, so that the filling of the additive, and thus an optimized utilization of the exhaust gas treatment system, can be ensured. There is thus already an existing distribution night of liquid additives, which reduces the availability of additives when the vehicle is driven.
Additives in liquid form can be refueled at many filling stations / gas stations where fuel is provided, so that the filling of the additive, and thus an optimized utilization of the exhaust gas treatment system, can be ensured.
According to another embodiment, the system 370 provides the other 372 metering device with gaseous additives. Depending on the embodiment, this additive can consist of hydrogen gas H2 and / or ammonia gas NH3.
An example of such a supply additive system 370 is shown schematically in Figure 3a, where the system comprises the second metering device 372, which is arranged upstream of the second reduction catalyst 332. The second metering device 372, which often consists of a metering nozzle dosing additives to, and mixing these additives with, the exhaust gas stream 303, supply additive of the at least one pump 373 via additive lines 375. The at least one pump 373 receives the additive from one or more additive tanks 376 via one or more lines 377 between the tank 32 (s) 376 and the at least one pump 373. It will be appreciated that the additive may be in liquid and / or gaseous form, such as described above. When the additive is in liquid form, the pump 373 is a liquid pump and the one or more tanks 376 are liquid containers. When the additive is in gaseous form, the pump 373 is a gas pump and the one or more tanks 376 are gas containers. If both gaseous and liquid additives are used, several tanks and pumps are provided, at least one tank and pump being provided for providing liquid additives and at least one tank and pump being provided for providing gaseous additives.
The specific function of the additive system 370 is described in the prior art, and the exact procedure for injecting additives is not further described. In general, however, the temperature at the injection point / SCR catalyst should be above a subsurface temperature to avoid precipitation and the formation of undesirable by-products, such as ammonium nitrate NH @ Mh. An example of a value for such a sub-branch value temperature may be about 200 ° C. According to one embodiment of the invention, the additive supply system 370 comprises a metering control unit 374 arranged to control the at least one pump 373 so that the additive feed is supplied to the exhaust gas stream. The dosing control unit 374 comprises, in one embodiment, a second pump control unit 379 arranged to control the at least one pump 373 so that a second dosing of the additive is supplied to the exhaust gas stream 303 via the second dosing device 372.
The one or more pumps 373 are thus controlled by a dosing control unit 374, which generates control signals for controlling the supply of additives so that the desired amount 33 is injected into the exhaust gas stream 303 by means of the second reduction catalyst device 332.
The metering control unit 374 may also be coupled to the control unit 360 which is arranged to provide control signals to the internal combustion engine 301. The control unit 360 thereby bases the creation of these control signals on information from the metering control unit 374, so that the view is added to the metering of the combustion engine control unit 301.
It should be noted that the exhaust gas treatment system according to the embodiment shown in Figure 3a need not have a subdivision upstream of the first reduction catalyst device 311, since the first reduction in the first reduction catalyst device 331 may be performed based on carbon monoxide and / or hydrocarbon HC compounds incorporated naturally or created by gas.
Figure 3b schematically shows an exhaust gas treatment system 350 according to an embodiment of the present invention which treats exhaust gases generated during combustion in the engine 301. Figure 3b has a large number of components of the common exhaust gas treatment system shown in Figure 3a and described above. These common components in Figure 3b have corresponding functions as described above for Figure 3a, and are therefore not described in detail for Figure 3b.
The exhaust gas treatment system according to the embodiments shown in Figure 3b thus comprises the features of the embodiments shown in Figure 3a. In addition, the exhaust gas treatment system according to the embodiment shown in Figure 3b further comprises a system 370 for supplying additives, which comprises at least one pump 373 arranged to supply the first dosing device 371 with compounds 34 comprising carbon monoxide CO and / or hydrocarbons HC, and to supply the second dosing device 372 with additives, that is to say with, for example, ammonia or urea.
According to one embodiment, the system 370 provides at least one of the first 371 and second 372 dosing devices carbon monoxide CO and / or the hydrocarbons HC and additives, respectively, in liquid form.
Additives in liquid form can be refueled at many filling stations / gas stations where fuel is provided, so the refilling of the additive can be refueled. The compounds comprising carbon monoxide CO and / or the hydrocarbons HC can also be refueled at certain filling stations / gas stations, for example in the form of diesel, natural gas, biogas or biogas. makes these associations available pretty much everywhere.
This means that an optimized utilization of both the first and the second dosing device is reliably provided at the edge in different types of operation. The optimized utilization, for example, is not limited to the first dosing device only being used for cold starts. There is thus already an existing distribution network for liquid additives and for the associations, which supply access to additives and compounds where the vehicle is driven.
The secondary emissions of the total exhaust gas treatment system, for example ammonia NH3, nitrogen dioxide NO2 and / or nitrous oxideN2O during normal operation of the internal combustion engine, i.e. only in cold starts, can be reduced by using one embodiment of the present invention by dosing carbon monoxide CO and / or hydrocarbon HC the first dosing device 371 and by dosing the additive at the second dosing device 372. However, when using the embodiment, this presupposes that a substantially continuous dosing is possible to provide. Utilizing additives and the compounds in liquid form made the additive racks without interruption for service, since additives and the compounds in liquid form are available to buy ordinary gas stations. Thereby, a substantially continuous dosing can be provided with both the first 371 and second 372 dosing devices during the entire normal service intervals of a vehicle.
The possibility of substantially continuous dosing with both the first 371 and second 372 dosing devices enables the exhaust gas treatment system to be utilized to its full potential. Thus, the system can be controlled so that robust and very high total degrees of NOX conversion can be obtained overtime, without the system having to take height for the additives and / or CO / HC compounds to run out. The fact that the supply of additives and / or the compounds makes a reliable control of the NO2 content NO2 / NOX can always be carried out, that is to say during the entire service intervals.
According to another embodiment, the system 370 provides at least one of the first 371 and second 372 dosing devices CO / HC compounds and gaseous additives, respectively. According to one embodiment, the additive may have consisted of hydrogen gas H2 and / or ammonia gas NH3.
An example of such a supply additive system 370 is shown schematically in Figure 3b, where the system includes the first metering device 371 and the second metering device 372, which are arranged upstream of the first reduction catalyst 331 and upstream of the second reduction catalyst 332. The first and second metering devices, often consists of 36 metering nozzles that dispense CO / HC compounds or additives to, and mix with, the exhaust stream 303, CO / HC compounds and additives are provided by at least one pump 373 via line 375 additives. The at least one pump 373 receives the CO / HC compounds or the additive from two or more tanks 376a-b via two or more lines 377 the intermediate tanks 376a-b and the at least one pump 373. It must be remembered that the CO / HC compounds and the additive respectively can be stored in liquid form and / or in gaseous form, as described above. When CO / HC compounds and the additive, respectively, are in liquid form, the pump 373 is a liquid pump and the two or more tanks 376a-b are liquid containers. When the CO / HC compound or additive is in gaseous form, the pump 373 is a gas pump and the two or more tanks 376a-b are gas containers. If both gaseous and liquid CO / HC compound-respective additives are used, several tanks and pumps are provided, at least one tank and pump being provided with pre-supply of liquid CO / HC compounds and additives, respectively, and at least one tank and pump being provided with pre-supply of gaseous CO / HC compounds. respective additives.
According to the embodiment shown in Figure 3b, compounds comprising carbon monoxide CO and / or the hydrocarbons HC are present in the exhaust stream 303 when it reaches the first reduction catalyst device 311 which have been discharged by the internal combustion engine 301 and which have been fed to the exhaust stream by the submersible device 371. arranged to effect reduction of nitrogen oxides NOX in the exhaust stream 303 by utilizing these compounds 37 comprising carbon monoxide CO and / or hydrocarbons HC present in the exhaust stream.
According to an embodiment of the invention, the at least one pump 373 comprises a common pump which feeds both the first 371 and the second 372 dosing device with CO / HC compounds and additives, respectively. According to another embodiment of the invention, the at least one pump comprises a first and a second pump, which feed the first 371 and the second 372 dosing device, respectively, with the CO / HC compounds and the additive, respectively.
The specific function of the additive system 370 is described in the prior art, and the exact procedure for injecting additives is not further described. In general, however, the temperature at the injection point / SCR catalyst should be above a subsurface temperature to avoid precipitation and the formation of undesirable by-products, such as ammonium nitrate NH @ Mh. An example of a value for such a sub-branch value temperature may be about 200 ° C. According to one embodiment of the invention, the additive supply system 370 comprises a metering control unit 374 arranged to control the at least one pump 373, so that CO / HC compounds and additives are supplied to the exhaust stream. According to one embodiment, the metering control unit 374 comprises a first pump control unit 378 arranged at least one pump control unit 378. in such a way that a first dose of CO / HC compounds is supplied to the exhaust gas stream 303 via the first metering device 371. The metering control unit 374 also includes a second pump control unit 379 arranged to control the at least one pump 373 in such a manner that a second dose of the additive is fed to the second metering stream 303 The one or more pumps 373 are thus controlled by a single-dose control unit 374, which generates control signals for controlling the supply of CO / HC compounds or additives so that the desired amount is injected into the exhaust gas stream 303 by means of the first 371 re. respectively the second 372 metering device upstream of the first 331 and second 322 reduction catalyst devices, respectively. In more detail, the first pump control unit 378 is arranged to control either a single pump, or a pump dedicated to the first metering device 371, whereby the first metering is controlled to supply the exhaust gas stream 303 via the pre-metering device 371. The second pump control unit 379 is arranged to control either a common pump, or a for the second metering device 372 dedicated pump, whereby the second metering device is controlled to be supplied to the exhaust gas stream 303 via the second metering device 372.
The metering control unit 374 may also be coupled to the control unit 360 which is arranged to provide control signals to the internal combustion engine 301. Thereby the control unit 360 can base the creation of these control signals on information from the metering control unit 374, so that the view is directed to the metering of CO / HC compounds. , and vice versa.
A robustness against failure of metered amounts of CO / HC compounds can be achieved by an embodiment of the invention, where a NOX sensor 363 is located between the two metering devices 371, 372, and preferably between the particle filter 320 and the other metering device 372, in the exhaust gas treatment system 350. it is possible to correct by means of the second dosing device 372 a possible dosing error 39 which has created unforeseen emission levels downstream of the first reduction device 371 and / or the particle filter 320.
This positioning of the NOX sensor 363 between the two dosing devices 371, 372, and preferably the intermediate particle filter CDPF 320 and the second dosing device 372, also makes it possible to correct the amount of additive dosed by the second dosing device 372 nitrogen oxides NOX which according to one embodiment can be created with CD catalytic coating of excess residues of CO / HC compounds from the dosing performed by the first dosing device 371.
The NOX sensor 364 downstream of the second reduction catalyst device 332 can be used in feedback of dosing of the additive.
By utilizing the exhaust gas treatment system 350 shown in Figures 3a-b, both the first reduction catalyst device 331 and the second reduction catalyst device 332 can be optimized with respect to the choice of catalyst characteristics for reducing nitrogen oxides NOX and / or with respect to volumes for the first 331 reduction or 332 catalyst. By the present invention, the particulate filter 320 is advantageously utilized in the pre-function by taking into account how its thermal mass affects the temperature of the second reduction catalyst332. For those embodiments where the particulate filter has a catalytic coating CDPF, the function of the particulate filter CDPF can also be used as an advantage by considering how the catalytic coating affects the NO 2 / NOX content upstream of the second reduction catalyst 332 in the exhaust gas purification.
By taking into account the thermal inertia of the pre-particle filter 320, the first reduction catalyst device 331 and the second reduction catalyst device 332, respectively, can be optimized with respect to the specific temperature function they will each experience. Since the optimized first 331 and second 332 reduction catalyst devices are arranged to co-operate with the exhaust gases of the present invention, the exhaust gas treatment system 350 can be made compact. When the space set aside for the exhaust gas treatment system 350, for example in a vehicle, is limited, it is a great advantage to provide a compact exhaust gas treatment system by a high degree of utilization of the catalysts used according to the present invention. This high degree of utilization, and the associated smaller volume language, also provides the opportunity for slightly reduced back pressure and thus also for lower fuel consumption.
The present invention provides a exhaust gas treatment system 350 which effectively reduces the amount of nitrogen oxides NOX in the exhaust stream at substantially all driving cases, including especially cold starts and load applications, i.e. at increased requested torque, from low exhaust temperature, total load deduction, i.e. at reduced required torque. Thus, the exhaust gas treatment system 350 of the present invention is suitable for substantially all driving cases which give rise to a transient temperature course in the exhaust gas treatment. An example of such a driving case can be city driving, which includes many starts and decelerations.
The prior art problems associated with excessive nitrogen dioxide NO2 can be solved at least in part by utilizing the present invention, since two reduction catalyst devices 371, 372 are included in the 41 exhaust gas treatment system 350. The problem can be addressed by combining the present invention with the insight that proportion of nitrogen dioxides NO2 which is maintained downstream of a filter and / or substrate coated with encatalytic oxidizing coating, that is to say that the amount of nitrogen oxides NOX can be used to control the value of the ratio NO2 / NOX. By reducing the nitrogen oxides NOX above the first reduction catalyst device 371 at operating low temperature, a requirement for a given ratio of intermediate nitrogen dioxide and nitrogen oxides NO2 / NOX in the exhaust gases reaching the second reduction catalyst device 372 can be met with less, and thus less expensive, amount of oxidizing coating.
The present invention has an advantage in that the additional manufacturing cost as a result of the invention can be kept at a low level, since the oxidation catalyst DOC 210 found in prior art systems in the manufacture according to one embodiment of the invention can be replaced by the amplifier reduction catalyst device 331 according to the present invention. According to an embodiment of the present invention, a first dosing device is also not required, since the first reduction in the further reduction catalyst device 331 takes place by reactions with carbon monoxide CO and / or the hydrocarbons HC which are naturally present or are introduced / introduced into the exhaust gas stream. Thus, one manufacturing step comprising mounting the oxidation catalyst DOC 210 can be easily replaced with another manufacturing step previously comprising mounting the first reduction catalyst device 331 according to the present invention. This provides a minimal addition to the assembly and / or manufacturing cost. Since the oxidation catalyst DOC 210 present in prior art systems can be replaced with the amplifier catalyst catalyst device 331 according to the present invention, retrofitting to already manufactured units including exhaust gas treatment systems according to the EuroVI specification is also possible.
For certain embodiments of the present invention, as described above, a first metering device 371 utilizes pre-dosing of carbon monoxide CO and / or the hydrocarbons HC. Thus, compounds comprising carbon monoxide CO and / or the hydrocarbons HC released from the engine and / or with the suburban metering device 371 are utilized in the reduction in the submerged reduction catalyst device. For these embodiments it is also required that an additional dosing device be mounted in the exhaust gas treatment system.
According to an embodiment, the first reduction catalyst device 331 in the exhaust gas treatment system 350 is active at a reduction temperature range T For example, the reduction temperature range Tn fl may be lower than the oxidation temperature range TM, whereby the temperature for so-called "light-off" for the sotoxidation in the particulate filter 320 may be higher than the "light-off" for the reduction of nitrogen oxides NOX in the first reduction catalyst reduction device. 331 not necessarily with the sotoxidation in the particulate filter 320 because they are active in at least partially different temperature ranges; Tæd # TM. 43 The exhaust gas treatment system sometimes requires, through control signals created in the control unit 360, that the engine should create heat for the exhaust gas treatment system to be able to achieve a sufficient efficiency with regard to exhaust gas purification. This heat generation is then achieved at the expense of reducing the engine's efficiency with respect to fuel consumption. An advantageous feature of the exhaust gas treatment system according to the present invention is that the first reduction catalyst device upstream of the filter can be made to react more quickly to this heat generated than has been possible for, for example, the Euro VI system. Therefore, overall fuel consumption is reduced by utilizing the present invention.
According to an embodiment of the present invention, the control motor for generating such heat to an extent so that the first reduction catalyst device reaches a certain sensor temperature / performance. Thus, an efficient exhaust gas purification can then be maintained by the first reduction catalyst device being able to operate at a favorable temperature, at the same time as an unnecessarily large heating, and thus industry efficiency, is avoided.
Unlike the aforementioned prior art solutions, the first reduction catalyst device 331 of the present invention need not be anesthetized to the engine and / or turbo. The fact that the first reduction catalyst device 331 according to the present invention can be mounted longer from the engine and / or turbo, and for example can be located in the muffler, has an advantage in that a longer mixing track is obtained in the exhaust stream between the engine and / or the turbo and the first reduction catalyst device 331. utilization rate is obtained for the amplifier reduction catalyst device 331. At the same time, the present invention obtains the many advantages mentioned in this document of having the possibility of reducing nitrogen oxides 10 44 NOX both upstream and downstream of the thermally inert filter CDPF.
According to various embodiments of the present invention, the first reduction catalyst device 331, which is arranged to reduce nitrogen oxides NOX by utilizing compounds comprising one or more of carbon monoxide CO and the carbonates HC, is constituted by any of: a first catalytic reduction catalyst CR1; a first catalytic reduction catalyst CR1 downstream of a first abrasive catalyst SC1, wherein the first abrasive catalyst SC1 is arranged to oxidize and / or decompose residues of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC, to be CR2 helpful in further reduce nitrogen oxides NOX in the exhaust stream 303 and / or create an exotherm; a first slip catalyst SC1 downstream followed by a first catalytic reduction catalyst CR1, wherein the first slip catalyst SC1 is arranged to oxidize compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC and / or to assist the first catalytic reduction catalyst CR¿ with a reduction of nitrogen oxides NOXi exhaust gas stream 303; and - a first slip catalyst SC1, which is primarily arranged for the reduction of nitrogen oxides NOX and secondly for the oxidation of a residue of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC.
According to various embodiments, the second reduction catalyst device 332, which performs a reduction of nitrogen oxides NOX at least in part by using an additive, is constituted by any of: a second selective catalytic reduction catalyst SCR2; and - a second selective catalytic reduction catalyst SCR2 10 downstream followed by a second grinding catalyst SC2, wherein the second grinding catalyst SC2 is arranged to oxidize a residual additive, where the residue may consist for example of urea, ammonia NH3 or isocyanic acid HNCO, and / or to assist SCR2 with a further reduction of NOX nitrogen oxides in the exhaust stream 303.
In this document, the term first slip catalyst SC1 is generally used for a first catalyst which is arranged to oxidize and / or probe CO and / or HC compounds in the exhaust stream 303 and / or which is arranged to be able to reduce residues of nitrogen oxides NOX in the exhaust stream 303 by utilizing CO and / or HC compounds in the exhaust stream. According to an embodiment of the present invention, such a first abrasive catalyst SC1 is arranged to primarily reduce nitrogen oxides NOX and secondarily to oxidize and / or subdivide the compounds, i.e. the first abrasive catalyst SC1 is a multifunctional slip catalyst. In other words, the multifunctional first slip catalyst SC1 can handle grinding residues of the compounds and / or can handle grinding residues of nitrogen oxides NOX. This can also be described as the first abrasive catalyst SC1 being a utocadammonia abrasive catalyst ASC, which is also designed for preoxidation and / or soot division of CO and / or HC compounds and for reduction of nitrogen oxides NOX in the exhaust stream 303, whereby a general / multifunctional first slip catalyst SC1 is created which takes care of several types of slip, ie takes care of both nitrogen oxides NOX and / or residues of CO and / or HC compounds.
According to one embodiment of the present invention, for example, at least the following reactions may be carried out in a first multifunctional grinding catalyst SC1 included in the first 10 46 reduction catalyst device 331 which reduces nitrogen oxides NOX and / or oxidizes compounds: Hc + 02 9 H 2 O + CO 2; (Eq. 3) Hc + NO 2 9 N 2 + CO 2; (Eq. 4) and / or co + NO2 9 NO2 + c02. (Eq. 5) In these simplified reaction formulas, HC corresponds to one or more hydrocarbon compounds CJH. Has gives the reaction according to Equation 3 an oxidation of the hydrocarbons HC. The reactions according to equations 4 and 5 give a reduction of nitrogen oxides NOW whereby HC and CO, respectively, are used in the reduction.
In order to obtain these properties, that is to say to retain a first multifunctional abrasive catalyst SC1 the abrasive catalyst according to one embodiment comprises one or more substances contained in the platinum metals (PGM; PlatinumGroup Metals), i.e. one or more of iridium, osmium, palladium , platinum, rhodium and ruthenium. The abrasive catalyst SC1 may also comprise one or more other substances which give the abrasive catalyst similar properties to the forplatin metal group. The slip catalyst may also comprise a NOX-reducing coating, where the coating may, for example, comprise Zeolite or Vanadium. Zeolite may have been activated with active metal, such as, for example, copper (Cu) or iron (Fe).
The slip catalyst SC1 may also include silver Ag.
For the first 33l reduction catalyst device, its catalytic properties can be selected based on the environment to which it is, or will be, exposed. In addition, the decatalytic properties of the first 331 and second 332 reduction catalyst devices can be adjusted so that they can be allowed to operate in symbiosis with each other. The first reduction catalyst device may further comprise one or more materials which provide that catalytic property. For example, transition metals such as Vanadino and / or Tungsten can be used, for example in a catalyst comprising V 3 h / WO 3 / TiO 2. Metals such as iron and / or copper can also be included in the first reduction catalyst device, for example in a zeolite-based catalyst. Silver Ag and / or platinum metals PGM can also be included in the first reduction catalyst, such as the name OVän.
In this document, the term second grinding catalyst SC2 is generally used for a catalyst which is arranged to oxidize and / or probe additives in the exhaust stream 303 and / or which is arranged to be able to reduce residues of nitrogen oxides NOX in the exhaust stream 303. The additive may, as mentioned above, comprise one or more of urea, ammonia NH3 and isocyanic acid HNCO. According to an embodiment of the present invention, such a second abrasive catalyst SC2 is arranged to first reduce nitrogen oxides NOX and secondarily to oxidize and / or probe a residue of additives, i.e. the second abrasive catalyst SC2 is a multifunctional abrasive catalyst. In other words, the second multifunctional abrasive catalyst SC2 can take care of abrasive residues of additives and / or can take care of abrasive residues of nitrogen oxides NOX. This can also be described as the second grinding catalyst SC2 is an unsaturated ammonia grinding catalyst ASC, which is also provided for oxidation and / or odor division of additives and reduction of nitrogen oxides NOXi the exhaust stream 303, whereby a general / multifunctional second grinding catalyst SC2 is obtained takes care of several types of lO 48 slip, that is to say takes care of nitrogen oxides NOX and / or residues of additives.
According to one embodiment of the present invention, for example, at least the following reactions may be carried out in a multifunctional second grinding catalyst SC2 included in the second reduction catalyst device 332, which reduces nitrogen oxides NOX and / or oxidizes additives: NH 3 + Og à Ng; (Eq. And / or NOX -I- NH3 9 Ng -1- H2O. (Eq. 7) Has gives the reaction according to Equation 6 an oxidation additive, for example residues of additives which include ammonia. The reaction according to Equation 7 gives a reduction of nitrogen oxides NOX. may have the additive, such as residues of ammonia NH3, isocyanic acid HNCO, urea or the like, oxidized.These residues of the additive, i.e. ammonia NH3, HNCO, urea or the like, may additionally have been used to reduce nitrogen oxides NOX.
In order to obtain these properties, i.e. to retain a multifunctional abrasive catalyst, the second abrasive catalyst SC2 according to one embodiment may comprise one or more substances included in the platinum metals (PGM; Platinum Group Metals), i.e. one or more aviridium, osmium, palladium, platinum, rhodium and ruthenium. The abrasive catalyst may also include one or more other substances which give the abrasive catalyst similar properties to the preplatinum metal group. The slip catalyst may also comprise a NOX-reducing coating, where the coating may, for example, comprise Zeolite or Vanadium. Zeolite may have been activated with an active metal, such as, for example, copper (Cu) or iron (Fe).
For the second 332 reduction catalyst device, its catalytic properties can be selected based on the environment it is exposed to, or will be exposed to. In addition, the decatalytic properties of the first 331 and second 332 reduction catalyst devices can be adjusted so that they are allowed to operate in symbiosis with each other. The second reduction catalyst device may further comprise one or more materials which provide that catalytic property. For example, transition metals such as Vanadino and / or Tungsten can be used, for example in a catalyst comprising V 3 h / WO 3 / TiO 2. Metals such as iron and / or copper can also be included in the first 331 and / or second 332 reduction catalyst device, for example in a zeolite-based catalyst.
The exhaust gas treatment system 350 shown schematically in Figures 3a-b can according to different embodiments have a variety of different structures / configurations, which can be summarized according to the following paragraphs, and where each unit CR1, SCR2, DPF, cDPF, SC1, SC2 has the respective properties shown in these documents. . A traditional particulate filter, that is to say an uncoated particulate filter, is called DPF. A particulate filter 320 having an at least partially catalytic oxidizing coating is designated cDPF. The catalytic oxidizing coating can be adapted to its properties to oxidize nitric oxide NO and oxidize incompletely oxidized carbon compounds. Incompletely oxidized carbon dioxide sheets, for example, are fuel residues created by the engine's injection system. According to a configuration according to the invention, the exhaust gas treatment system comprises the structure CR1-cDPF-SCR2. It is understood that the exhaust gas treatment system 350 comprises a first catalytic reduction catalyst CR1, downstream followed by a particle filter cDPF with an at least partially catalytic oxidizing coating, downstream followed by a second selective catalytic reduction catalyst SCR2. A symbiotic utilization of the first catalytic reduction catalyst CR1 and the second selectively catalytic reduction catalyst SCR2 in the exhaust gas treatment system 350 may allow a second slip catalyst SC2 to be omitted in the exhaust gas treatment system 350 for certain applications, for example at limited limited NOX levels. This is an advantage, for example, compared with the above-mentioned EuroVI system, in which the grinding catalyst is in practice a requirement. Since an SCR catalyst is typically cheaper than an SC catalyst by this embodiment, the manufacturing cost is reduced by omitting the second grinding catalyst SC2. The first catalytic reduction catalyst CR1 can be used to generate heat, for example by oxidizing the hydrocarbons HC in the exhaust stream. regeneration of sulfur-contaminated components, such as the first catalytic reduction catalyst CR2 and / or downstream devices. During the regeneration of the sulfur-contaminated components, the amount of sulfur stored in the components is reduced, i.e. in at least one of the first catalytic reduction catalyst CR¿ and downstream of these arranged components.
The utilization of the particle filter cDPF 320 comprising the deoxidizing coating provides an improved NO2-based regeneration of the filter, more stable conditions for the nitrogen dioxide level N02 at the second reduction catalyst device 332 and / or an opportunity to control the value of the NO2 / NOX ratio.
According to a configuration according to the invention, the exhaust gas treatment system comprises the structure CR2-SC1-cDPF-SCR2. That is, the exhaust gas treatment system 350 comprises a first catalytic reduction catalyst CR1, downstream followed by a first slip catalyst SC1, downstream followed by a particle filter cDPF with an at least partially catalytic oxidizing coating, downstream followed by a second selective catalytic catalytic reduction2. As mentioned above, the use of both the first catalytic reduction catalyst CR2 and the second selective catalytic reduction catalyst SCR2 in the exhaust gas treatment system 350 makes it possible that the second slip catalyst SC2 can be omitted in the exhaust gas treatment system 350 for certain applications, which anchors the manufacturing cost of the vehicle. The utilization of the first grinding catalyst SC1 enables a greater load, and thus a better utilization, of the first catalytic reduction catalyst CR1.
According to an embodiment of the present invention, the first reduction catalyst device 331 comprises a first-slip catalyst SC1 which is multifunctional, thereby reducing nitrogen oxides NOX by utilizing residual compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC and also oxidizing and / or decomposing residues ( above). This has a number of advantages for the exhaust gas treatment system. The first grinding catalyst SC1 may have been used in symbiosis with the first reduction catalyst CR1 so that the activity of the first grinding catalyst SC1 with respect to reduction of nitrogen oxides NOX and oxidation and / or decomposition of residues of the compounds, and the grinding catalyst SC1 storage characteristics of the compounds , complements the function of the first reduction catalyst CR1. The combination of these properties of the first reduction catalyst device 331 including the first reduction catalyst CR2 and the first grinding catalyst SC1 allows a higher degree of conversion to be obtained over the first reduction catalyst device 331. In addition, the grinding catalyst SC1 in the first reduction catalyst device 331 conditions for avoiding an unselective oxidation of CO / HC compounds within components of the first reduction catalyst device 331 located in the exhaust gas treatment system.
The first catalytic reduction catalyst CR2 and / or the first abrasive catalyst SC1 can be used for the purpose of generating heat, for example by oxidizing the hydrocarbon HC in the exhaust gas stream, which enables regeneration of sulfur-contaminated components, such as the first catalytic reduction catalyst CR2 and / or downstream components thereof. During the regeneration of the sulfur-contaminated components, the amount of sulfur stored in the components is reduced, i.e. in at least one of the first catalytic reduction catalyst CR¿ and downstream of these arranged components.
The utilization of the particle filter CDPF 320 comprising the deoxidizing coating provides an improved NO 2 -based regeneration of the filter, more stable conditions for the nitrogen dioxide level NO 2 at the second reduction catalyst device 332 and / or an opportunity to control the value of the NO 2 / NOX ratio. According to a configuration according to the invention, the exhaust gas treatment system comprises the structure CR1-cDPF-SCR2-SC2. It is understood that the exhaust gas treatment system 350 comprises a first catalytic reduction catalyst CR1, downstream followed by a particle filter cDPF with an at least partially catalytic oxidizing coating, downstream followed by a second selective catalytic reduction catalyst SCR2, downstream followed by a SC2. This exhaust gas treatment system 350 enables emission levels of nitrogen oxides NOX close to zero, since the second reduction catalyst SCR2 can be heavily loaded, for example by increasing the dosage of the additive, when it is followed downstream by the second grinding catalyst SC2. Utilization of the second grinding catalyst SC2 since additional slip can be taken care of by the second slip catalyst SC2.
The first catalytic reduction catalyst CR1 can be used for the purpose of generating heat, for example by oxidizing the hydrocarbons HC in the exhaust stream, which enables regeneration of sulfur-contaminated components, such as the first catalytic reduction catalyst CR1 and / or downstream of these device components. In the regeneration of the sulfur-contaminated components, the amount of sulfur stored in the components is reduced, i.e. in at least one of the first catalytic reduction catalyst CR2 and downstream of these components. The use of the particle filter cDPF 320 comprising the oxidizing filter coating N2 provides a stable coating. the nitrogen dioxide level N02 at the second reduction catalyst device 332 and / or an option to control the value of the NO2 / NOX ratio. According to a configuration according to the invention, the exhaust gas treatment system comprises the structure CR1-SC1-cDPF-SCR2-SC2. That is, the exhaust gas treatment system 350 includes a first catalytic reduction catalyst CR1, downstream followed by first grinding catalyst SC1, downstream followed by a particle filter cDPF with an at least partially catalytic oxidizing coating, downstream followed by a second selective catalyst catalytic reduction catalyst followed by SC. This exhaust gas treatment system 350 enables emission levels for nitrogen oxides NOX near zero, since the second reduction catalyst SCR2 can be driven hard, for example by increasing the dosage of the additive, as it is followed downstream by the second grinding catalyst SC2. The use of the second grinding catalyst SC2 provides further improved radar performance for the system, as additional grinding can be taken care of by the second grinding catalyst SC2. The use of the second slip catalyst SC2 also enables a lowering of the starting temperature ("light off" temperature) for the NOX reduction and can also give a greater load and thus better utilization of the second selective catalytic reduction catalyst SCR2.
According to one embodiment, the first reduction catalyst device 331 comprises an abrasive catalyst SC1 described above which is multifunctional, and thus reduces nitrogen oxides NOX by utilizing residual compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC and also oxidizes and / or decomposes the residues as described above. ). This has a number of advantages for the exhaust gas treatment system. The first slip catalyst SC1 may have been used in symbiosis with the first reduction catalyst CR1 so that the activity of the first slip catalyst SC1 with respect to reduction of nitrogen oxides NOX and oxidation and / or probing of residues of the CO / HC compounds, and grinding The SC1 storage characteristic of the catalyst for the CO / HC compounds is a complement to the function of the pre-reduction catalyst CR1. The combination of these properties of the first reduction catalyst device 331, including the first reduction catalyst CR1 and the first grinding catalyst SC1, results in a higher degree of conversion being obtained over the first reduction catalyst device331. In addition, the use of the first slip catalyst SC1 in the first reduction catalyst device 331 provides conditions to prevent an unselective oxidation of CO / HC compounds in the components located downstream of the first reduction catalyst device 331 in the exhaust gas treatment system.
The first catalytic reduction catalyst CR1 and / or the first grinding catalyst SC1 can be used for the purpose of generating heat, for example by oxidizing the hydrocarbon HC in the exhaust gas stream, which enables regeneration of sulfur-contaminated components, such as the first catalytic reduction catalyst CRs and / or downstream components. During the regeneration of the sulfur-contaminated components, the amount of sulfur stored in the components is reduced, i.e. in at least one of the first catalytic reduction catalyst CR¿ and downstream of these arranged components.
The utilization of the particle filter cDPF 320 comprising the deoxidizing coating provides an improved NO 2 -based regeneration of the filter, more stable conditions for the nitrogen dioxide level NO 2 at the second reduction catalyst device 332 and / or an option to control the value of the NO 2 / NOX ratio. According to a configuration according to the invention, the exhaust gas treatment system comprises the structure SC1-cDPF-SCR2. That is, the exhaust gas treatment system 350 comprises a first slip catalyst SC1, downstream followed by a particulate filter cDPF with an at least partially catalytic oxidizing coating, downstream followed by a second selective catalytic reduction catalyst SCR2. Also, due to the utilization of both the first slip catalyst SC1 and the other selectively catalytic reduction catalyst SCR2, the second slip catalyst SC2 may be omitted in the exhaust gas treatment system 350 for certain applications.
According to one embodiment of the present invention, the first reduction catalyst device 331 comprises only a slip catalyst SC1 which is multifunctional and both reduces nitrogen oxides NOX by utilizing compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC and also oxidizes and / or decomposes the compounds (as This provides a number of advantages). described above). the exhaust gas treatment system.
The first abrasive catalyst SC1 can be used for the purpose of generating heat, for example by oxidizing the hydrocarbons HC in the exhaust gas stream, which enables regeneration of sulfur-contaminated components, such as the catalyst and / or downstream of these arranged components. During the regeneration of the sulfur-contaminated components, the amount of sulfur stored in the components is reduced.
The utilization of the particle filter cDPF 320 comprising the oxidizing coating provides an improved NO 2 -based regeneration of the filter, more stable conditions for the nitrogen dioxide level NO 2 at the second 10 reduction catalyst device 332 and / or an opportunity to control the value of the NO 2 / NOX ratio.
According to a configuration according to the invention, the exhaust gas treatment system comprises the structure SC1-cDPF-SCR2-SC2. That is, the exhaust gas treatment system 350 comprises a first slip catalyst SC1, downstream followed by a particulate filter cDPF with an at least partially catalytic oxidizing coating, downstream followed by a second selective catalytic reduction catalyst SCR2, downstream followed by a second slip catalyst SC2. This exhaust gas treatment system 350 enables emission levels for nitrogen oxides NOX close to zero, since the other reduction catalyst SCR2 can be heavily loaded, i.e. with a relatively high dosage of the additive, as it is followed downstream by the second grinding catalyst SC2. The use of the second grinding catalyst SC2 provides further improved radar performance for the system, as additional grinding can be taken care of by the second grinding catalyst SC2. The use of the second slip catalyst SC2 enables a lowering of the starting temperature (“light off” temperature) for the NOX reduction.
According to one embodiment of the present invention, the first reduction catalyst device 331 comprises only a slip catalyst SC1 which is multifunctional and both reduces nitrogen oxides NOX by utilizing compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC and also oxidizes and / or decomposes the compounds (as described above). This brings a number of advantages to the pre-exhaust gas treatment system. The first grinding catalyst SC1 can be used for the purpose of generating heat, for example by oxidizing the hydrocarbons HC in the exhaust gas stream, which enables regeneration of sulfur-contaminated components, such as the catalyst and / or components arranged downstream thereof. During the regeneration of the sulfur-contaminated components, the amount of sulfur stored in the components is reduced.
The utilization of the particle filter cDPF 320 comprising the deoxidizing coating provides an improved NO 2 -based regeneration of the filter, more stable conditions for the nitrogen dioxide level NO 2 at the second reduction catalyst device 332 and / or an option to control the value of the NO 2 / NOX ratio.
According to a configuration according to the invention, the exhaust gas treatment system comprises the structure SC1-CR1-cDPF-SCRQ. That is, the exhaust gas treatment system 350 includes a pre-grinding catalyst SC1, downstream of a first catalytic reduction catalyst CR1, downstream of a single particle filter cDPF with an at least partially catalytic oxidizing coating, downstream of a second selective catalytic reduction catalyst. As mentioned above, the use of both the first catalytic reduction catalyst CR2 and the second selective catalytic reduction catalyst SCR2 in the exhaust gas treatment system 350 allows the second slip catalyst SC2 to be omitted in the exhaust gas treatment system 350 for certain applications, which anchors the manufacturing cost. The utilization of the first grinding catalyst SC1 enables a greater load and thus a better utilization of the first catalytic reduction catalyst CR1.
According to one embodiment of the present invention, the first reduction catalyst device 331 comprises an abrasive catalyst SC1 which is multifunctional, thereby reducing nitrogen oxides NOX by utilizing compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC, and also oxidizing and / or probing the compounds (as described above). , which brings a number of advantages to the pre-exhaust gas treatment system. The first grinding catalyst SC1 can be used in symbiosis with the first reduction catalyst CR1 so that the activity of the first grinding catalyst SC1 with respect to reduction of nitrogen oxides NOX and oxidation additives, as well as the grinding catalyst SC1 storage characteristic of the CO / HC compounds, is a complement to the function for the first reduction catalyst CR1. The combination of these properties for the first reduction catalyst device 331 including the first reduction catalyst CR1 and for the first grinding catalyst SC1 results in a higher degree of conversion being obtained over the first reduction catalyst device331. In addition, the use of the first slip catalyst SC1 in the first reduction catalyst device 331 provides conditions for preventing an unselective oxidation of CO / HC compounds from occurring in components downstream of the first reduction catalyst device 331 in the exhaust gas treatment system.
The first catalytic reduction catalyst CR1, and / or the first grinding catalyst SC1 can be used for the purpose of generating heat, for example by oxidizing the hydrocarbons HC in the exhaust gas stream, which enables regeneration of sulfur-contaminated components, such as the catalyst and / or downstream of these arranged components. During the regeneration of the sulfur-contaminated components, the amount of sulfur stored in the components is reduced. The utilization of the first grinding catalyst SC1 upstream of the first catalytic reduction catalyst CR¿ provides good opportunities to create this heat.
The utilization of the particle filter cDPF 320 comprising the oxidizing coating provides an improved NO 2 -based 10 regeneration of the filter, more stable conditions for the nitrogen dioxide level NO 2 at the second reduction catalyst device 332 and / or an opportunity to control the value of the NO 2 / NOX ratio.
According to a configuration according to the invention, the exhaust gas treatment system comprises the structure SC1-CR1-CDPF-SCR2-SC2. That is, the exhaust gas treatment system 350 comprises a first slip catalyst SC1, downstream followed by a first catalytic reduction catalyst CR1, downstream followed by a particle filter CDPF with an at least partially catalytic oxidizing coating, downstream followed by a second selective catalyst catalytic catalytic reductionR22. This exhaust gas treatment system 350 enables emission levels for nitrogen oxides NOX near zero, since the second reduction catalyst SCR2 can be driven hard, for example by increasing the dosage of the additive, as it is followed downstream by the second grinding catalyst SC2. The utilization of the second slip catalyst SC2 also enables a lowering of the starting temperature ("light off" temperature) for the NOX reduction and can also give a greater load and thus better utilization of the second selective catalytic reduction catalyst SCR2. The utilization of the second grinding catalyst SC2 further improves the performance of the pre-system, since additional grinding can be taken care of by the second grinding catalyst SC2.
According to one embodiment of the present invention, the first reduction catalyst device 331 comprises an abrasive catalyst SC1 which is multifunctional, and thus reduces nitrogen oxides NOX by utilizing compounds including carbon monoxide and / or the hydrocarbons HC and also oxidizing and / or decomposing the compounds (as described above). benefits of the exhaust gas treatment system. 61 The first grinding catalyst SC1 may have been used in symbiosis with the first reduction catalyst CR1 so that the activity of the first grinding catalyst SC1 with respect to reduction of nitrogen oxides NOX and oxidation and / or decomposition of CO / HC compounds, and the grinding catalyst SC1 storage characteristics for CO / HC compounds, are a complement to the function of the first reduction catalyst CR1. The combination of these properties for the first reduction catalyst device 331 including the first reduction catalyst CR1 and for the first grinding catalyst SC1 results in a higher degree of conversion being obtained over the first reduction catalyst device331. In addition, the use of the first slip catalyst SC1 in the first reduction catalyst device 331 provides conditions for preventing an unselective oxidation of CO / HC compounds from occurring in components downstream of the first reduction catalyst device 331 in the exhaust gas treatment system.
The first catalytic reduction catalyst CR2 and / or the first abrasive catalyst SC1 can be used for the purpose of generating heat, for example by oxidizing the hydrocarbon HC in the exhaust gas stream, which enables regeneration of sulfur-contaminated components, such as the catalyst and / or downstream arranged components. During the regeneration of the sulfur-contaminated components, the amount of sulfur stored in the components is reduced. The utilization of the first grinding catalyst SC1 upstream of the first catalytic reduction catalyst CR¿ provides good opportunities to create this heat.
In the above-listed configurations according to the embodiments, the first reduction catalyst CR1 and the first grinding catalyst SC1 may be an integrated unit 62 comprising both CR1 and SC1, or may be separate units for CR1 and SC @ Similarly, the first reduction catalyst device 331 and the particulate filter CDPF an at least partially catalytic oxidizing coating is constituted by an integrated unit comprising both the first reduction catalyst device 331 and the particulate filter CDPF, or may be separate units for the first reduction catalyst device 331 and the filter CDPF.
Correspondingly, the second reduction catalyst SCR2 and the second grinding catalyst SC2 can either consist of an integrated unit comprising both SCR2 and SC2, or can consist of separate units for SCR2 and SC2.
Correspondingly, the first abrasive catalyst SC1 and the particle filter CDPF 320 with an at least partially catalytic oxidizing coating may constitute at least partially integrated units or comprise separate units.
The above-described configurations of the invention may include various embodiments of the present invention including a first oxidation catalyst DOC1 311 disposed upstream of the first reduction catalyst 331 to perform a first oxidation of compounds comprising one or more of nitrogen, carbon and hydrogen in said exhaust stream 303, as described above. The configurations can thus be briefly described as DOC1-CR1-CDPF-SCR2, DOC1-CR1-CDPF-SCR2-SC2, DOC1-CR1-SC1-CDPF-SCR2, DOC1-CR1-SC1-cDPF-SCR2-SC2, DOC1-SC1- CDPF-SCRQ, DOC1-SC1-CDPF-SCR2-SC2, DOC1-SC1-CR1-CDPF-SCRQ, DOC1-SC1-CR1-cDPF-SCR2-SC2.
The configurations of the invention described above may, according to various embodiments of the present invention, also comprise 63 a second oxidation catalyst 312 arranged downstream of the first reduction catalyst device 331 and upstream of an uncoated particle filter DPF 320 to carry out a second oxidation of compounds comprising one or more of said nitrogen. exhaust stream 303, as described above. The configurations can then be briefly described according to CR1-DOC2-DPF-SCRQ, CR1-DOC2-DPF-SCR2-SC2, CR1-SC1-DOC2-DPF-SCR2, CR1-SC1-DOC2-DPF-SCR; -SC2, SC1 -DOC2-DPF-SCR2, SC1-DOC2-DPF-SCRQ-SC2, SC1-CR1-DOC2-DPF-SCR2, SC1-CR1-DOC2-DPF-SCR2-SC2; respectively DOC1-CR1-DOC2-DPF-SCR2, DOC1-CR1-DOC2-DPF-SCR2-SC2, DOC1-CR1-SC1-DOC2-DPF-SCR2, DOC1-CR1-SC1-DOC2-DPF-SCR2-SC2, DOC1 -SC1-DOC2-DPF-SCR2, DOC1-SC1-DOC2-DPF-SCR2-SC2, DOC1-SC1-CR1-DOC2-DPF-SCR2, DOC1-SC1-CR1-DOC2-DPF-SCR2-SC2.
The above-described inventive configurations according to various embodiments of the present invention include a third oxidation catalyst 313 disposed downstream of a coated cDPF or uncoated DPF particulate filter320 and upstream of the second reduction catalyst device 322 to perform a second oxidation of compounds comprising one or more compounds comprising 303, as described above. The configurations can thus be briefly described according to CR1-cDPF-DOC3-SCR2, CR1-CDPF-DOC3-SCR2-SC2, CR1-SC1-CDPF-DOC3-SCR2, CR1-SC1-cDPF-DOC3-SCRQ-SC2, SC1-CDPF -DOC3-SCR2, SC1-CDPF-DOC3-SCRQ-SC2, SC1-CR1-CDPF-DOC3-SCR2, SC1-CR1-CDPF-DOC3-SCRQ-SC2; respectively DOC1-CR1-CDPF-DOC3-SCR2, DOC1-CR1-CDPF-DOC3-SCR2-SC2, DOC1-CR1-SC1-cDPF-DOC3-SCR2, DOC1-CR1-SC1-CDPF-DOC3-SCR2-SC2, DOC1 -SC1-cDPF-DOC3-SCR2, DOC1-SC1-CDPF-DOC3-SCR2-SC2, DOC1-SC1-CR1-CDPF-DOC3-SCR2, DOC1-SC1-CR1-CDPF-DOC3-SCR2-SC2; CR1-DOC2-DPF-DOC3-SCR2, CR1-DOC2-DPF-DOC3-SCR2-SC2, CR1-SC1-DOC2-DPF-DOC3-SCR2, CR1-SC1-DOC2-DPF-DOC3-SCR2-SC2, SC1-DOC2-DPF-DOC3-SCR2, SC1-DOC2-DPF-DOC3-SCR2-SC2, SC1-CR1-DOC2-DPF-DOC3-SCR2, SC1-CR1-DOC2-DPF-DOC3- 64 SCR2-SC2; respectively DOC1-CR1-DOC2-DPF-DOC3-SCR2, DOC1-CR1-DOC2-DPF-DOC3-SCRQ-SC2, DOC1-CR1-SC1-DOC2-DPF-DOC3-SCR2, DOC1-CR1-SC1-DOC2-DPF -DOC3-SCR2-SC2, DOC1-SC1-DOC2-DPF-DOC3-SCR2, DOC1-SC1-DOC2-DPF-DOC3-SCR2-SC2, DOC1-SC1-CR1-DOC2-DPF-DOC3-SCR2, DOC1-SC1 -CR1-DOC2-DPF-DOC3-SCR2-SC2. Also the above-described configurations according to the invention which do not comprise a second oxidation catalyst DOC2 according to different embodiments of the present invention also include an uncoated particle filter DPF 320. The configurations can then be briefly described according to CR1-DPF-SCR2, CR1-DPF-SCRQ-SC1, CR1-DP1-SCRQ-SC2, CR1-DPF-SCR2. -DPF-SCR2, CR1-SC1-DPF-SCR2-SC2, SC1-DPF-SCR2, SC1-DPF-SCRQ-SC2, SC1-CR1-DPF-SCRQ, SC1-CR1-DPF-SCR2-SC2; respectively DOC1-CR1-DPF-SCR2, DOC1-CR1-DPF-SCR2-SC2, DOC1-CR1-SC1-DPF-SCR2, DOC1-CR1-SC1-DPF-SCR2-SC2, DOC1-SC1-DPF-SCR2, DOC1 -SC1-DPF-SCR2-SC2, DOC1-SC1-CR1-DPF-SCR2, DOC1-SC1-CR1-DPF-SCR2-SC2; respectively CR1-DPF-DOC3-SCR2, CR1-DPF-DOC3-SCR2-SC2, CR1-SC1-DPF-DOC3-SCR2, CR1-SC1-DPF-DOC3-SCR2-SC2, SC1-DPF-DOC3-SCR2, SC1 -DPF-DOC3-SCR2-SC2, SC1-CR1-DPF-DOC3-SCR2, SC1-CR1-DPF-DOC3-SCR; -SC2; respectively DOC1-CR1-DPF-DOC3-SCR2, DOC1-CR1-DPF-DOC3-SCRQ-SC2, DOC1-CR1-SC1-DPF-DOC3-SCR2, DOC1-CR1-SC1-DPF-DOC3-SCRQ-SC2, DOC1 -SC1-DPF-DOC3-SCR2, DOC1-SC1-DPF-DOC3-SCR2-SC2, DOC1-SC1-CR1-DPF-DOC3-SCR2, DOC1-SC1-CR1-DPF-DOC3-SCR2-SC2.
As described in detail above, each of the above inventive configurations may include a second metering device 371 upstream of the second reduction catalyst device 332, and include or not include a first metering device 371 upstream of the first reduction catalyst device 331.
According to one aspect of the present invention, there is provided a method of treating an exhaust stream 303 emitted by an internal combustion engine 301. This method is described with the aid of Figure 4, in which the process steps follow the flow of the exhaust stream through the exhaust treatment system 350.
In a first step 410 of the process, a reduction of nitrogen oxides NOX in the exhaust stream is carried out by utilizing compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC which are included in the exhaust stream 303 of a first reduction catalyst device 331. The first reduction catalyst device 331 may contain different embodiments. or a first slip catalyst SC1. The first grinding catalyst SC1 is arranged to oxidize and / or decompose the CO / HC compounds and / or give a further reduction of nitrogen oxides NOX in the exhaust gas stream 303. It should be noted that the reduction of nitrogen oxides NOX by the first reduction catalyst device 331 in this partial document may include lange as the total reaction constitutes a reduction of nitrogen oxides NOX.
In a second step 420 of the process, the exhaust stream is filtered, soot particles being captured and oxidized by a particulate filter 320. In various embodiments, this particulate filter 320 may be a conventional uncoated particulate filter DPF, or a particulate filter CDPF which at least partially comprises a catalytic oxidizing coating. oxidizing coating oxidizes the trapped soot particles and one or more incompletely oxidized nitrogen and / or carbon compounds.
In a third step 430 of the process, a supply of additive to the exhaust gas stream 303 is controlled by the use of a second metering device 372.
In a fourth step 440 of the process, a reduction of the nitrogen oxides NOX in the exhaust stream 303 is carried out by utilizing at least the additive in a second reduction catalyst device 332, which may comprise another selective catalytic reduction catalyst SCR2 and in some configurations a second grinding catalyst device SC1. The reduction in which the second reduction catalyst 332 is affected has the addition of additives in the third stage 430. The second slip catalyst SC2 oxidizes has an excess of additive, such as for example ammonia, and / or gives a further reduction of nitrogen oxides NOX in the exhaust stream 303. It should be noted that the reduction of nitrogen oxides NOX by means of the second reduction catalyst device 332 in this document may comprise partial oxidation as long as the total reaction constitutes a reduction of nitrogen oxides NOX.
It can be seen that a first temperature T1 to which the first reduction catalyst device 331 is exposed and a second temperature T2 to which the second reduction catalyst device 332 is exposed are of great importance to the operation of the exhaust gas treatment system 350. However, it is difficult to regulate these temperatures T1, T2, as this largely depends on how the driver in front of the vehicle, i.e. the first T1 and second T2 temperatures depend on the actual operation of the vehicle and on input via, for example, an accelerator pedal in the vehicle.
The exhaust gas treatment process and the self-exhaust gas treatment system 350 are considerably more efficient than a traditional system (as shown in Figure 2) in that the first temperature T1 of the first reduction catalyst device 331, for example at start-up processes, earlier reaches higher care for that first temperature T1, thereby reducing efficiency. NOX by the process of the present invention. Thus, a more effective reduction of nitrogen oxides NOX is obtained, for example at cold starts and at start-ups from low exhaust temperatures, which results in a reduced increase in fuel consumption in such driving cases. In other words, the present invention utilizes the difficult-to-control first T1 and second T2 temperatures to its advantage in such a way as to contribute to increasing the overall efficiency of the exhaust gas purification system.
The above-mentioned advantages of the exhaust gas treatment system 350 are also obtained for the process of the present invention.
According to one embodiment of the present invention, an exhaust 401 is controlled by compounds comprising one or more carbon monoxide CO and the hydrocarbons HC in the exhaust stream 303 from the internal combustion engine 301. For this embodiment, the reduction 410 of nitrogen oxides NOX in the exhaust stream 303 is utilized by the first reduction catalyst stream 331. carbon monoxide CO and the hydrocarbons HC. According to this embodiment of the present invention, there are thus provided one or more control signals which can be used in controlling the internal combustion engine 301 so that a desired amount of the compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC is released to the exhaust stream 303 from the internal combustion engine 301. the reduction in the first reduction catalyst device.
According to an embodiment of the present invention, one or more control signals are also provided which can be used to control the internal combustion engine 301 so that heat for heating the first reduction catalyst device 68 331 is created to such an extent that the first reduction catalyst device 331 reaches a predetermined, and for its function suitable, temperature.
According to one embodiment of the present invention, mono supply 402 is controlled by compounds comprising one or more carbon monoxide CO and the hydrocarbons HC to the exhaust stream 303 utilizing a first metering device 371 disposed downstream of the internal combustion engine 301 and upstream of the first reduction catalyst device 331. first step 410 these added compounds. Thus, the first reduction catalyst 331 utilizes one or more of the added compounds including carbon monoxide CO and / or the hydrocarbon HC. Thus, according to this embodiment, the exhaust gas treatment system 350 comprises a pre-metering device 371. One or more control signals which can be used to control the supply of carbon monoxide and / or hydrocarbon compounds with the first metering device 371 are provided.
According to an embodiment of the present invention, one or more control signals are provided which can be used to control both emissions from the engine 301 and the supply to a first dosing device 371. Thus, one outlet 401 is controlled by compounds comprising one or more carbon dioxide CO and the hydrocarbons HC in the exhaust stream 303 from the internal combustion engine 301. A supply 402 of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC in the exhaust stream 303 is also controlled by utilizing a pre-metering device 371 arranged downstream of the internal combustion engine 301 and upstream of the first reduction catalyst device 331. The reduction 410 of nitrogen oxides NOX in the exhaust gas stream 303 by means of the first reduction catalyst device 331 69 takes place by utilizing one or more of these feed compounds and these released compounds. The feed compounds and the released compounds include, as described above, one or more of carbon monoxide CO and the hydrocarbons HC.
According to the above-described embodiments of the present invention, 402 is provided by one or more control signals which may be used to control the internal combustion engine 301 to obtain a desired amount of compounds comprising carbon monoxide CO and / or hydrocarbons HC in the exhaust stream or to retain heat to heat the first order reduction catalyst. These one or more control signals may have been created by the control unit 360 and provided to the motor 301, as illustrated in Figures 3a-b.
Correspondingly, the control unit 360 can create the above-mentioned one or more control signals for controlling the supply of compounds comprising carbon monoxide CO and / or the hydrocarbons HC in the exhaust gas stream and supply them to the dosing control unit 374, as illustrated in Figure 3b.
As mentioned above, according to an embodiment of the present invention, the first abrasive catalyst SC1 may be a multifunctional abrasive catalyst, which both reduces nitrogen oxides NOX and oxidizes residues of CO / HC compounds, for example by primarily reducing nitrogen oxides NOX and secondarily oxidizing residues of CO / HC compounds. To retain these properties, the first abrasive catalyst SC1 according to one embodiment may comprise one or more substances comprising the platinum metal group and / or silver Ag.
Such a multifunctional first grinding catalyst SC1 included in the first reduction catalyst device 331, according to an embodiment of the invention alone can constitute the first reduction catalyst device 331, i.e. the first reduction catalyst device 331 consists only of the multifunctional grinding catalyst SC1.
Such a multifunctional first grinding catalyst SC1 included in the first reduction catalyst device 331, according to another embodiment of the invention in combination with a first reduction catalyst CR1 may constitute the first reduction catalyst device 331, i.e. the first reduction catalyst device CR1 consists of the first reduction catalyst -catalyst SC1.
As mentioned above, according to an embodiment of the present invention, the second abrasive catalyst SC2 may be a multifunctional abrasive catalyst, which both reduces nitrogen oxides NOX and oxidizes residues of additives, for example by primarily reducing nitrogen oxides NOX and secondly oxidizing additive residues.
In order to obtain these properties, the second abrasive catalyst SC2 according to one embodiment may comprise one or more substances contained in the platinum metals and / or one or more other substances which gives the abrasive catalyst similar properties as for the platinum metal group.
For the second grinding catalyst SC2 in the second reduction catalyst device 332, oxidation residues of additives which have passed through the second reduction catalyst SCR2 are often only substantially obtained, since only low levels of nitrogen oxides NOX have are available in the exhaust stream 303. 71 The multifunctional second grinding catalyst at least two active layers / layers arranged on at least one stabilizing layer / structure 601, which is shown schematically in Figure 6. It should be noted that the embodiment shown in Figure 6 is only an example of a possible design of a multifunctional second grinding catalyst SC2. A multifunctional second grinding catalyst SC2 can be formed in a number of second ways, as long as the reactions described above are effected by the multifunctional second grinding catalyst SC2. Thus, a number of designs, in addition to that shown in Figure 6, of the multifunctional second grinding catalyst SC2, which provide an oxidation of additives, as well as a reduction of nitrogen oxides NOX, can be used for the multifunctional second grinding catalyst SC2.
The first layer 602 of these active layers comprises the second abrasive catalyst SC2 one or more substances contained in the platinum metals, or one or more other substances, which gives the abrasive catalyst similar properties to the platinum metal group, i.e. for example oxidation of ammonia. The second 603 layer may comprise a NOX-reducing coating, for example comprising Zeolite or Vanadine. Zeolite is activated with an active metal, such as copper (Cu) or iron (Fe). The second layer 603 is in direct contact with the exhaust stream 303 passing through the exhaust gas treatment system.
According to an embodiment of the present invention, the first reduction catalyst device 331, i.e. the first grinding catalyst SC1 and / or the further reduction catalyst CR1 can thus be used for oxidation of the hydrocarbons HC and / or carbon monoxide CO, which occur naturally and / or are created / introduced in the exhaust stream. For example, hydrocarbons HC in the exhaust gas stream 303 may include fuel residues from the combustion in the internal combustion engine 101 and / or from additional injections of fuel in connection with regeneration of the particle filter DPF / CDPF.
The oxidation of the hydrocarbon HC in the first reduction catalyst device 331 may also comprise at least one exothermic reaction, i.e. a reaction which generates heat so that a temperature rise of the first reduction catalyst device 331 and / or downstream subsequent components such as the particle filter DPF / cDPF 350.This temperature rise can be used in sotoxidation in the particulate filter DPF / cDPF 320 and / or in order to remove the re-vapor from by-products, such as urea. This at least one exothermic reaction enables the deoxidation of the hydrocarbons HC in the amplifier reduction catalyst device 331. In addition, the CR layer in the first grinding catalyst SC1 can be deactivated over time by, for example, sulfur, which means that a heat-generating exotherm may be required. slip catalyst SC1. Correspondingly, a heat-generating exotherm can be used to ensure the function of a supernatant catalyst CR1 by single regeneration. As mentioned above, the regeneration reduces the amount of sulfur in the catalyst / component that IGgGnGIGIäS.
The above-mentioned properties and advantages stated for a single multifunctional grinding catalyst SC1 in the amplifier reduction catalyst device 331 can be made to operate very selectively for an exhaust gas treatment system 350 as described above, i.e. with a first reduction catalyst device 331 downstream followed by a particulate filter. may be partially coated with catalytic coating, 320 downstream followed by a second reduction catalyst device 332.
According to an embodiment of the process of the present invention, the reduction is controlled by means of the first reduction catalyst device 331 to take place within a reduction temperature range Tn with the nitrogen dioxide-based sotoxidation in the particle filter DPF / CDPF.
According to one embodiment of the process, the first reduction catalyst device 331 is optimized based on properties, such as catalytic properties, for the first 331 and / or other 332 reduction catalyst device. In addition, the use of the second reduction catalyst device 332 can be optimized based on properties, such as catalytic properties, of the first 331 and / or the second 332 reduction catalyst device. These possibilities for optimizing the first reduction catalyst device and / or the second reduction catalyst device provide entotally efficient exhaust gas purification which better takes into account the conditions of the complete exhaust gas treatment system.
The above-mentioned properties of the first 331 and / or second 322 reduction catalyst device may be related to one or more of the catalytic properties of the first 331 and / or second 332 reduction catalyst device, single catalyst type of the first 331 and / or second 332 reduction catalyst device, a temperature range within which the first 331 and / or second 332 reduction catalyst device is active and a degree of filling of CO / HC and ammonia, respectively, for the first 331 and second 332 reduction catalyst device, respectively.
According to an embodiment of the present invention, the first reduction catalyst device 331 and the second reduction catalyst device 332, respectively, are optimized based on the operating conditions of the first 331 and second 332 reduction catalyst devices, respectively. These operating conditions can be related to a temperature, i.e. a static temperature, for the first 331 and the second 332 reduction catalyst device, respectively, and / or to a temperature temperature trend, i.e. a change in temperature, for the first 331 and the second 332 reduction catalyst device, respectively.
According to an embodiment of the process of the present invention, an active control of the reduction performed by the first reduction catalyst device 331 is performed based on a ratio between the amount of nitrogen dioxide NO¿¿ and the amount of nitrogen oxides NO & ¿reaching the second reduction catalyst device 332. In other words, the ratio NO & ¿to have a value suitable for the reduction in the second reduction catalyst device 332, whereby a more effective reduction can be obtained. Thus, in more detail, the first reduction catalyst device 311 has a first reduction of a first amount of nitrogen oxides NO & ¿which reaches the first reduction catalyst device 331. The second reduction catalyst device 332 is then performed a second reduction of a second amount of nitrogen oxides NO & ¿which reaches a second reduction catalyst. the ratio NO¿¿ / NO & ¿between the amount of nitrogen dioxide NO¿¿ and the second amount of nitrogen oxides NO & ¿which reach the second reduction catalyst device 332. This adjustment is performed by using an active control of the first reduction based on a fixed value (NO¿¿ / NO & ¿) M fi for the NO¿¿ / NO & ¿ratio, with the intention of giving the NO¿¿ / NO & ¿ratio a value that makes the other reduction more efficient. The value (NO¿¿ / NO & ¿) m% for the ratio NO¿¿ / NO & ¿may have consisted of a measured value, a modeled value and / or a predicted value. A predicted value can be determined based on a representation of a vehicle section lying in front of the vehicle. This representation can be based, for example, on positioning information, such as GPS information, and map data.
According to one embodiment of the process of the present invention, a first oxidation of compounds comprising one or more of the nitrogen, carbon and hydrogen exhaust gas stream 303 is performed. This first oxidation is then performed by a first oxidation catalyst 311 arranged upstream of the first reduction catalyst 332.
According to one embodiment of the process of the present invention, a second oxidation of compounds comprising one or more of the nitrogen, carbon and hydrogen exhaust gas stream 303 is performed. This second oxidation is then performed by a second oxidation catalyst 312 arranged downstream of the first reduction catalyst 332 and upstream of the particulate filter 320. -coated particle filter DPF.
According to one embodiment of the process of the present invention, a third oxidation of compounds comprising one or more of the nitrogen, carbon and hydrogen exhaust gas stream 303 is performed. This third oxidation is then performed by a third oxidation catalyst 313 arranged downstream of the particulate filter 320 and upstream of the second reduction catalyst device.
According to another embodiment of the present invention, the particle filter cDPF 320 comprises at least partially encatalytic oxidizing coating arranged for oxidizing the or more of nitric oxide NO and incompletely oxidized carbon compounds in the exhaust stream.
Those skilled in the art will appreciate that a method of processing an exhaust gas present invention may additionally be implemented in a computer program, which when executed in a computer causes the computer to perform the procedure. The computer program usually forms part of a computer program product 503, the computer program product comprising a suitable digital non-volatile / durable / permanent / permanent storage medium on which the computer program is stored. Said computer-readable non-volatile / durable / durable / permanent media consist of a flash memory, such as: ROM (Read-Only Memory), PROM (Programmable Read-Only Memory), EPROM (Erasable PROM), Flash memory, EEPROM (Electrically Erasable PROM), a hard disk drive, etc.
Figure 5 schematically shows a control unit 500. The control unit 500 comprises a computing unit 501, which can be essentially any suitable type of processor or microcomputer, e.g. a Digital SignalProcessor (DSP), or an Application Specific Integrated Circuit (ASIC). The computing unit 501 is connected to a memory unit 502 arranged in the control unit 500, which provides the computing unit 501 e.g. the stored program code and / or the stored data the computing unit 501 needs to be able to perform calculations. The calculation unit 501 is also arranged to store part or end results of calculations in the memory unit 502.
Furthermore, the control unit 500 is provided with devices 511, 512, 513, 514 for receiving and transmitting input and output signals, respectively. These input and output signals may contain waveforms, pulses, or other attributes, which the input signals receiving devices 511, 513 are detected as information and can be converted into signals which can be processed by the estimating unit 501. These signals are then provided to the estimating unit 501. The output signals 512,514 are arranged to convert calculation results from the calculation unit 501 to output signals for transmission to other parts of the vehicle control system and / or the component (s) for which the signals are intended.
Each of the connections to the devices for receiving or transmitting input and output signals, respectively, may be one or more of a cable; a data bus, such as a CAN bus (Controller Area Network bus), a MOST bus (Media OrientatedSystems Transport bus), or any other bus configuration; or by a wireless connection.
One skilled in the art will appreciate that the above-mentioned computer may be the defragmentation unit 501 and that the above-mentioned memory may be the memory unit 502.
In general, control systems in modern vehicles consist of a communication bus system consisting of one or more communication buses for interconnecting a number of electronic control units (ECUs), or controllers, and various components located on the vehicle. Such a control system can comprise a large number of control units, and the responsibility for a specific function can be divided into more than one control unit. Vehicles of the type shown thus thus comprise 78 often considerably more control units than what is shown in Figure 5, which is the choice for the person skilled in the art.
As will be appreciated by those skilled in the art, the controller 500 of Figure 5 may include one or more of the controllers 115 and 160 of Figure 1, the controller 260 of Figure 2, the controller 360 of Figures 3a-b and the controller 374 of Figures 3a-b.
The present invention is in the embodiment shown implemented in the control unit 500. However, the invention can also be fully or partially implemented in one or more other control vehicles already existing in the control unit or in any control unit dedicated to the present invention.
This document often describes units, for example control units, as being arranged to perform steps in the method according to the invention. This also includes the attenuators adapted and / or arranged to perform these process steps. For example, these units may correspond to different groups of instructions, for example in the form of program code, which are entered into, and used by, a processor when each unit is active / used to perform the respective process steps.
Those skilled in the art will also appreciate that the above exhaust gas treatment system can be modified according to the various embodiments of the method of the invention. In addition, the invention relates to the motor vehicle 100, for example a passenger car, a truck or a bus, or another unit comprising at least one exhaust gas treatment system according to the invention, such as for instance a vehicle or a voltage / current generator.
The present invention is not limited to the embodiments of the invention described above, but relates to and includes all embodiments within the scope of the appended independent claims.

权利要求:
Claims (37)
[1]
Exhaust gas treatment system (350) arranged for treating an exhaust gas stream (303) resulting from a combustion in an internal combustion engine (301), characterized by - a first reduction catalyst device (331) arranged pre-reduction of nitrogen oxides NOX in said exhaust gas stream (303) utilizing compounds or several carbon dioxide CO and the hydrocarbons HC which are included in said exhaust gas stream (303) when said exhaust gas stream (303) reaches said first reduction catalyst device (331); a particulate filter (320) arranged downstream of said first reduction catalyst device (331) for capturing and oxidizing soot particles in said exhaust stream (303); - a second metering device (372) arranged downstream of said particulate filter (320) and arranged to supply an ammonia means or an amine from which ammonia can be recovered and / or released in said exhaust gas stream (303); and - a second reduction catalyst device (332) arranged downstream of said second dosing device (372) and arranged to reduce nitrogen oxides NOX in said exhaust gas stream (303) by using said additive.
[2]
The exhaust gas treatment system (350) of claim 1, wherein: - said internal combustion engine (301) is arranged to relax embodiments comprising one or more of carbon monoxide CO and the hydrocarbons HC in said exhaust stream (303); and - said first reduction catalyst device (331) arranged to reduce nitrogen oxides NOX in said exhaust gas stream (303) by utilizing at least said emission compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC in said exhaust gas stream (303). 80
[3]
Exhaust gas treatment system (350) according to any one of claims 1-2, wherein: - a first metering device (371) is arranged downstream of said combustion engine (301) and upstream of said first reduction catalyst device (331), and is arranged to supply compounds comprising one or more of carbon monoxide CO the hydrocarbon HC to said exhaust stream (303); and - said first reduction catalyst device (331) arranged to reduce nitrogen oxides NOX in said exhaust gas stream (303) by utilizing at least said feed compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC in said exhaust gas stream (303).
[4]
An exhaust gas treatment system (350) according to any one of claims 1-3, wherein: - said internal combustion engine (301) is arranged to relax embodiments comprising one or more of carbon monoxide CO and the hydrocarbons HC in said exhaust gas stream (303); a first metering device (371) is arranged downstream of said combustion engine (301) and upstream of said first reduction catalyst device (331), and is arranged to supply compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC to said exhaust stream (303); and - said first reduction catalyst device (331) arranged to reduce nitrogen oxides NOX in said exhaust gas stream (303) by utilizing one or more of said feed compounds and said released compounds, wherein said added compounds and said released compounds comprise one or more of carbon monoxide HC.
[5]
An exhaust gas treatment system (350) according to any one of claims 1-4, further comprising: - a control unit (360) arranged to provide one or more control signals which can be used in controlling said 81 internal combustion engine (301) to provide a desired plurality of naming compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC are to be released from said internal combustion engine (301).
[6]
An exhaust gas treatment system (350) according to any one of claims 1-5, wherein said first reduction catalyst device (331) comprises any one of the group of: - a first catalytic reduction catalyst (CRU) - a first catalytic reduction catalyst (CR1) downstream of a first slip catalyst (SC1) , wherein said first slip catalyst (SC1) is arranged to oxidize and / or decompose said compounds, to assist said first catalytic reduction catalyst (CR2) with a further reduction of nitrogen oxides NOX in said exhaust stream (303) and / or to create an exotherm; first slip catalyst (SC1) downstream followed by a first catalytic reduction catalyst (CR1), where the first slip catalyst (SC1) is arranged to oxidize and / or decompose said compounds, to assist said first catalytic reduction catalyst (CR¿) with a reduction in NOx said exhaust gas stream (303) and / or to create an exotherm, and - a first grinding catalyst (SC1) arranged to oxidize and / or to decompose said compounds, to provide a single reduction of nitrogen oxides NOX in said exhaust gas stream (303) and / or to create an exotherm.
[7]
An exhaust gas treatment system (350) according to any one of claims 1-6, wherein said second reduction catalyst device (332) comprises any one of the group of: - a second selective catalytic reduction catalyst (SCR fi; and 10 82 - a second selective catalytic reduction catalyst (SCR catalyst (SC2), wherein said second slip catalyst (SC2) is arranged to oxidize a residual additive and / or to assist said second selective catalytic reduction catalyst (SCR2) with a further reduction of nitrogen oxides NOX in said exhaust stream (303).
[8]
An exhaust gas treatment system (350) according to any one of claims 1 to 7, wherein said exhaust gas treatment system (350) comprises a system (370) for supplying one or more of said compounds comprising one or more of carbon monoxide CO, the hydrocarbons HC and said additives, said system ( 370) comprises at least one pump (373) arranged to pre-name the first (371) and second (372) dosing devices with said compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC and said additives, respectively.
[9]
The exhaust gas treatment system (350) of claim 8, wherein said system (370) for supplying one or more said compounds comprising one or more of carbon monoxide CO, the hydrocarbons HC and said additive comprises a dosing control unit (374) arranged to control said at least one pump ( 373).
[10]
An exhaust gas treatment system (350) according to claim 8, wherein said system (370) for supplying one or more said compounds comprising one or more of carbon monoxide CO, the hydrocarbons HC and said additive comprises a dosing control unit (374) comprising: - a first pump control unit (378 ) arranged to control said at least one pump (373), wherein a first dose of said compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC is supplied to said exhaust stream by using said first dosing device (371); and 83 - a second pump control unit (379) arranged to control said at least one pump (373), a second dose of said additive being supplied to said exhaust stream by utilizing said second dosing device (372).
[11]
An exhaust gas treatment system according to any one of claims 1-10, wherein said first reduction catalyst device (331) is arranged to reduce said nitrogen oxides NOX within a reduction temperature range Tn fl, which is at least partially different from an oxidation temperature range TM within which said particle filter (320) oxidized carbon compounds; Tæd # TM.
[12]
An exhaust gas treatment system according to any one of claims 1-11, further comprising: - a first oxidation catalyst (311) arranged upstream of said first reduction catalyst (331) for a first oxidation and / or probe division of compounds comprising one or more of nitrogen, carbon and cotton in said exhaust stream ( 303) and / or to create an exotherm.
[13]
An exhaust gas treatment system according to any one of claims 1 to 12, wherein said particulate filter (320) at least partially comprises a catalytic oxidizing coating arranged to oxidize one or more of nitric oxide NO and incompletely oxidized carbon compounds.
[14]
An exhaust gas treatment system according to any one of claims 1-13, wherein said particulate filter (320) at least partially comprises a catalytically reducing coating arranged to reduce nitrogen oxides NOX.
[15]
An exhaust gas treatment system according to any one of claims 1 to 14, further comprising a second oxidation catalyst (312) disposed downstream of said first 84 reduction catalyst device (331) and upstream of said particle filter (320) for a second oxidation and / or decomposition of compounds comprising one or more nitrogens, carbon and vate in said exhaust stream (303) and / or to create an exotherm.
[16]
An exhaust gas treatment system according to any one of claims 1 to 15, further comprising a third oxidation catalyst (313) disposed downstream of said particulate filter (320) and upstream of said second reduction catalyst device (332) for a third oxidation and / or decomposition of compounds comprising one or more of nitrogen, carbon and vate in said exhaust stream (303) and / or to create an exotherm.
[17]
A process for treating an exhaust gas stream (303) which results from a combustion in an internal combustion engine (301), characterized by - a reduction (410) of nitrogen oxides NOX in said exhaust gas stream by using a first reduction catalyst device (331), said reduction ( 410) is carried out by utilizing compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC which are included in said exhaust gas stream (303) called said exhaust stream when said first reduction catalyst device (331); and - a capture and oxidizing (420) of soot particles collected exhaust gas stream (303) by utilizing a particle filter (320), which is arranged downstream of the first reduction catalyst device (331); and - a control (430) of supply of an additive comprising ammonia or a substance from which ammonia can be recovered and / or released in said exhaust stream (303) by using a second dosing device (372) arranged downstream of said particle filter (320), wherein said supply of said additive affects a reduction (440) of nitrogen oxides NOX in said exhaust gas stream (303) by utilizing said additive in a second reduction catalyst device (332) arranged downstream of said second metering device (372).
[18]
The method of claim 17, wherein: - a release (401) of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC in said exhaust stream (303) is made from said internal combustion engine (301); and - said reduction (410) of nitrogen oxides NOX in said exhaust gas stream (303) by means of said first reduction catalyst device (331) utilizes said released compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC in said exhaust gas stream (303).
[19]
A method according to any one of claims 17-18, wherein: - a supply (402) of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC to said exhaust stream (303) is performed using a first dosing device (371) arranged downstream of said internal combustion engine. (301) and upstream of said first reduction catalyst device (331); and - said reduction (410) of nitrogen oxides NOX in said exhaust gas stream (303) by means of said first reduction catalyst device (331) utilizing said supplied compounds comprising one or more of the carbon monoxide CO and the hydrocarbons called exhaust gas (303).
[20]
A method according to any one of claims 17-19, wherein: - a release (401) of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC in said exhaust stream (303) 86 is made from said internal combustion engine (301); a supply (402) of compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC in said exhaust stream (303) is performed by using a first metering device (371) arranged downstream of said internal combustion engine (301) and upstream of said first reduction catalyst device (331); a reduction (410) of nitrogen oxides NOX in said exhaust gas stream (303) by said first reduction catalyst device (331) by utilizing one or more of said feed compounds and said released compounds, wherein said added compounds and said released compounds comprise one or more of carbon monoxide the hydrocarbon HC.
[21]
A method according to any one of claims 17-20, comprising: - a provision (402) of one or more control signals which may be used in controlling said internal combustion engine (301) to produce a desired amount of said compounds comprising one or more of carbon monoxide CO and the hydrocarbons HC must be released from the said internal combustion engine (301).
[22]
The method of any of claims 17-21, wherein said internal combustion engine (301) is controlled to generate heat preheating of said first reduction catalyst device (331) to such an extent that said first reduction catalyst device (331) reaches a predetermined temperature.
[23]
A process according to any one of claims 17-22, wherein said reduction (410) is controlled by means of said first reduction catalyst device (331) to take place within a reduction temperature range Tn fl, which is at least partially different from an oxidation temperature range TM within 87 which said oxidation of incompletely oxidized means 320) happens; Tæd # TOX.
[24]
A process according to any one of claims 17-23, wherein said reduction (410) of nitrogen oxides NOX by means of said pre-reduction catalyst device (331) is controlled based on one or more properties and / or operating conditions of said first reduction catalyst device (331).
[25]
A process according to any one of claims 17-24, wherein said reduction (410) of nitrogen oxides NOX by means of said pre-reduction catalyst device (331) is controlled based on one or more properties and / or operating conditions of said second reduction catalyst device (332).
[26]
A process according to any one of claims 17 to 25, wherein said reduction (440) is controlled by said second reduction catalyst device (372) based on one or more properties and / or operating conditions of said second reduction catalyst device (332).
[27]
A process according to any one of claims 17-26, wherein said reduction (440) is controlled by said second reduction catalyst device (332) based on one or more properties and / or operating conditions of said first reduction catalyst device (331).
[28]
A process according to any one of claims 14-27, wherein said properties of said first (331) and second (372) reduction catalyst devices are related to one or more in the group of: - catalytic properties of said further reduction catalyst device (331); - catalytic properties of said second 88 reduction catalyst device (332); a catalyst type for said first reduction catalyst device (331); a catalyst type for said second reduction catalyst device (332); a temperature range within which said first reduction catalyst device (331) is active; a temperature range within which said second reduction catalyst device (332) is active; - a degree of carbon dioxide and / or hydrocarbon fill for the first reduction catalyst device (331); and - an ammonia filling degree for said second reduction catalyst device (332).
[29]
A process according to any one of claims 17 to 28, wherein said first reduction catalyst device (331) performs a first reduction (410) of a first plurality of name nitrogen oxides NOA which reaches said first reduction catalyst device (331); - said second (440) reduction catalyst device (332) performs a second reduction of a second plurality of name nitrogen oxides NO & ¿which reaches said second reduction catalyst device (332); and - an adjustment is performed by a ratio NO¿¿ / NO & ¿between a quantity of nitrogen dioxide NO¿¿ and said second quantity of nitrogen oxides NO & ¿which reach said second reduction catalyst device (332), an active control of said first reduction (410) said first quantity nitrogen oxides NO & ¿are performed based on a value (NO¿¿ / NO & ¿) m% for the said ratio NO¿¿ / NO & ¿.
[30]
A method according to claim 29, wherein said value (NO¿¿ / NOÄ¿) m% for said ratio NO¿¿ / NO & ¿consists of a group of: - a measured value; 89 - a modeled value; - a predicted value.
[31]
A process according to any one of claims 17-30, further comprising: - a first oxidation of compounds comprising one or more of nitrogen, carbon and hydrogen in said exhaust gas stream (303) which is carried out by a first oxidation catalyst (311) arranged upstream of said first reduction catalyst (331 ).
[32]
A process according to any one of claims 17-31, further comprising: - a second oxidation of compounds comprising one or more of nitrogen, carbon and cotton in said exhaust gas stream (303) which is arranged by a second oxidation catalyst (312) arranged downstream of said first reduction catalyst (331) and upstream of said particle filter (320).
[33]
A process according to any one of claims 17-32, further comprising: - a third oxidation of compounds comprising one or more of nitrogen, carbon and hydrogen in said exhaust stream (303) which is carried out by a third oxidation catalyst (313) arranged downstream of said particulate filter (320) and upstream of said second reduction catalyst device (332).
[34]
A method according to any one of claims 17-33, wherein said particulate filter (320) comprises at least in part a catalytic oxidizing coating arranged for oxidizing one or more of nitrogen oxide NO and incompletely oxidized carbon compounds in said exhaust stream.
[35]
An exhaust gas treatment system according to any one of claims 17 to 34, wherein said particle filter (320) comprises at least partially 1090 a catalytically reducing coating arranged to reduce nitrogen oxides NOX.
[36]
A computer program comprising program code, said program code being executed in a computer causing said computer to perform the method of any of claims 17-35.
[37]
A computer program product comprising a computer readable medium and a computer program according to claim 36, wherein said computer program is included in said computer readable medium.

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法律状态:

优先权:

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申请号 | 申请日 | 专利标题

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SE1551109A|SE539134C2|2015-08-27|2015-08-27|Exhaust gas treatment system and method for treating an exhaust gas stream|SE1551109A| SE539134C2|2015-08-27|2015-08-27|Exhaust gas treatment system and method for treating an exhaust gas stream|

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KR1020187007504A| KR102157716B1|2015-08-27|2016-08-25|Exhaust treatment system and exhaust gas stream treatment method|

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RU2018109484A| RU2682203C1|2015-08-27|2016-08-25|Exhaust control system and method for cleaning exhaust gas flow|

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EP16839707.3A| EP3341598A4|2015-08-27|2016-08-25|Exhaust treatment system and method for treatment of an exhaust as stream|

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JP2018510514A| JP6776338B2|2015-08-27|2016-08-25|Exhaust treatment systems and methods for the treatment of exhaust gas flows|

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US15/750,168| US10807041B2|2015-08-27|2016-08-25|Exhaust treatment system and method for treatment of an exhaust gas stream|

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PCT/SE2016/050796| WO2017034465A1|2015-08-27|2016-08-25|Exhaust treatment system and method for treatment of an exhaust as stream|

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BR112018002015A| BR112018002015A2|2015-08-27|2016-08-25|exhaust treatment system and method of treating an exhaust gas stream|

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CN201680047426.XA| CN107923282B|2015-08-27|2016-08-25|Exhaust gas treatment system and method for treating an exhaust gas stream|